Infrared and Raman Spectra of Inorganic and Coordination Compounds: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, Vol. 52 Book

Preface to the Sixth Edition ix

Abbreviations xi

1 Applications in Coordination Chemistry 1

1.1 Ammine, Amido, and Related Complexes 1

1.2 Complexes of Ethylenediamine and Related Ligands 14

1.3 Complexes of Pyridine and Related Ligands 23

1.4 Complexes of Bipyridine and Related Ligands 29

1.5 Metalloporphyrins 37

1.6 Metallochlorins, Chlorophylls, and Metallophthalocyanines 45

1.7 Nitro and Nitrito Complexes 52

1.8 Lattice Water and Aquo and Hydroxo Complexes 57

1.9 Complexes of Alkoxides, Alcohols, Ethers, Ketones, Aldehydes, Esters, and Carboxylic Acids 62

1.10 Complexes of Amino Acids, EDTA, and Related Ligands 67

1.11 Infrared Spectra of Aqueous Solutions 74

1.12 Complexes of Oxalato and Related Ligands 79

1.13 Complexes of Sulfate, Carbonate, and Related Ligands 84

1.14 Complexes of [beta]-Diketones 96

1.15 Complexes of Urea, Sulfoxides, and Related Ligands 105

1.16 Cyano and Nitrile Complexes 110

1.17 Thiocyanato and Other Pseudohalogeno Complexes 120

1.18 Complexes of Carbon Monoxide 132

1.19 Complexes of Carbon Dioxide 152

1.20 Nitrosyl Complexes 155

1.21 Complexes of Dioxygen 161

1.22 Metal Complexes Containing Oxo Groups 175

1.23 Complexes of Dinitrogen and Related Ligands 183

1.24 Complexes of Dihydrogen and Related Ligands 189

1.25 Halogeno Complexes 193

1.26 Complexes Containing Metal-Metal Bonds 199

1.27 Complexes of phosphorus and Arsenic Ligands 206

1.28 Complexes of Sulfur and Selenium Ligands 210

References 222

2 Applications in Organometallic Chemistry 275

2.1 Methylene, Methyl, and Ethyl Compounds 275

2.2 Vinyl, Allyl, Acetylenic, and Phenyl Compounds 281

2.3 Halogeno, Pseudohalogeno, and AcidoCompounds 283

2.4 Compounds Containing Other Functional Groups 290

2.5 [pi]-Bonded Complexes of Olefins, Acetylenes, and Related Ligands 294

2.6 Cyclopentadienyl Compounds 302

2.7 Cyclopentadienyl Compounds Containing Other Groups 308

2.8 Complexes of Other Cyclic Unsaturated Ligands 313

2.9 Miscellaneous Compounds 318

References 319

3 Applications in Bioinorganic Chemistry 333

3.1 Myoglobin and Hemoglobin 335

3.2 Ligand Binding to Myoglobin and Hemoglobin 340

3.3 Cytochromes and Other Heme Proteins 350

3.4 Bacteriochlorophylls 359

3.5 Hemerythrins 363

3.6 Hemocyanins 368

3.7 Blue Copper Proteins 373

3.8 Iron-Sulfur Proteins 378

3.9 Interactions of Metal Complexes with Nucleic Acids 387

References 393

Index 403