Supercritical Carbon Dioxide: Separations and Processes Book

	Preface
1	An Introduction to Separations and Processes Using Supercritical Carbon Dioxide	2
2	Extraction of Uranium and Lanthanides from Their Oxides with a High-Pressure Mixture of TBP-HNO[subscript 3]-H[subscript 2]O-CO[subscript 2]	10
3	Supercritical Fluid Extraction fo Actinides and Heavy Metals for Environmental Cleanup: A Process Development Perspective	23
4	Supercritical Fluid Extraction of Plutonium and Americium from Soil using [beta]-Diketone and Tributyl Phosphate Complexants	36
5	Solubility and Modifications of Metal Chelates in Supercritical Carbon Dioxide	50
6	Extracting Gold in Supercritical CO[subscript 2]: Fluorinated Molecular Baskets and Thiourea Ligands for Au	67
7	Ligand-Assisted Extraction of Metals from Fly Ash with Supercritical CO[subscript 2]: A Comparison with Extraction in Aqueous and Organic Solutions	80
8	Coupled Processing Options for Agricultural Materials Using Supercritical Fluid Carbon Dioxide	104
9	Supercritical Fluid Extraction of Bioactive Components from St. John's Wort (Hypericum perforatum L.) and Ginkgo biloba	130
10	Hot Water Extraction Followed by Solid-Phase Microextraction of Active Ingredients in Rosemary: An Organic Solvent-Free Analytical Technique	145
11	Cleanup of Disperse Dye Contaminated Water by Supercritical Carbon Dioxide Extraction	157
12	Approaches to Soil Remediation with Green Procedures	172
13	Time-Resolved Laser-Induced Fluorescence Characterization of Uranium Complexes and Processes in ScF CO[subscript 2]	188
14	Solubilization Study by QCM in Liquid and Supercritical CO[subscript 2] under Ultrasonar	207
15	Uranyl Extraction by TBP from a Nitric Aqueous Solution to SC-CO[subscript 2]: Molecular Dynamics Simulations of Phase Demixing and Interfacial Systems	223
16	Experimental Measurement and Modeling of the Vapor-Liquid Equilibrium of [beta]-Diketones with CO[subscript 2]	245
17	Thermodynamics of the Baylis-Hillman Reaction in Supercritical Carbon Dioxide	259
18	Dissolving Carbohydrates in CO[subscript 2]: Renewable Materials as CO[subscript 2]-philes	270
19	Design and Performance of Surfactants for Carbon Dioxide	285
20	Nanoparticle Formation in Rapid Expansion of Water-in-Carbon Dioxide Microemulsion into Liquid Solvent	309
21	Fine Particle Pharmaceutical Manufacturing Using Dense Carbon Dioxide Mixed with Aqueous or Alcoholic Solutions	324
22	Nanocrystal Synthesis and Stablization in Supercritical Solvents	339
23	Supercritical Melt Micronization Using the Particles from Gas-Saturated Solution Process	353
24	Synthesis of Nanostructured Sorbent Materials Using Supercritical Fluids	370
25	Synthesis of Structured Polymeric Materials Using Compressed Fluid Solvents	387
26	Catalytic Hydrogenation of Olefins in Supercritical Carbon Dioxide Using Rhodium Catalysts Supported on Fluoroacrylate Copolymers	406
27	Hydrogenation Reactions in Supercritical CO[subscript 2] Catalyzed by Metal Nanoparticles in a Water-in-Carbon Dioxide Microemulsion	419
28	Hydroformylation of Olefins in Water-in-Carbon Dioxide Microemulsions	430
	Author Index	447
	Subject Index	449