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Abbreviations vii
Introduction 1
Chapter 1 The Nature of N-Heterocyclic Carbenes 7
1.1 Synthesis
1.1.1 Synthesis of the Imidazolium Salts
1.1.2 Closing the Ring
1.1.3 Synthesis of the Free Carbenes
1.1.4 Synthesis of Transition Metal Complexes of NHC
1.2 Properties of NHC
1.2.1 The Internal Electronic Structure
1.2.2 Basicity of NHC
1.2.3 Steric Properties
1.2.4 The Carbene-Metal Bond
1.2.5 Decomposition Pathways
References
Chapter 2 Why Functionalisation?
2.1 Phosphane Mimic
2.2 Hemilability
2.3 Chirality
2.3.1 Planar Chirality
2.3.2 Axial Chirality
2.4 Ligand Geometry
2.5 Catalysis
2.5.1 Allylic Alkylation
2.5.2 Coupling Reactions
2.5.3 Olefin Metathesis
2.5.4 Polymerisations
2.5.5 Organocatalysis
References
Chapter 3 N-Heterocyclic Carbenes with Neutral Tethers
3.1 Amine Functionalities
3.1.1 Heteroaromatic Functional Groups
3.1.2 Oxazolines
3.1.3 Imino Functional Groups
3.1.4 Amino Functionalised NHC
3.2 Oxygen-Containing Groups
3.3 Phosphane Functionalities
3.4 Bis-Carbene Ligands
3.5 Tris-N-Heterocyclic Carbene Ligands
3.6 Pincer Carbenes
References
Chapter 4 N-Heterocyclic Carbenes with Anionic Functional Groups 199
4.1 Oxygen-Containing Groups
4.2 Nitrogen-Containing Groups
4.3 NHC Ligands Incorporating Cp Moieties
4.4 Transition Metal NHC Complexes Involved in the Activation of C-H Bonds
4.5 Immobilisation of the Catalyst
4.6 Sulfur-Containing Functional Groups
References
Chapter 5 Chiral N-Heterocyclic Carbenes 279
References
Chapter 6 Natural Products 309
6.1 Thiazole
6.1.1 Isolation and Stability of Thiazolylidene
6.1.2 Benzothiazoles
6.1.3 Metal Complexes
6.2 Amino Acids
6.3 Purines and Xanthines
6.4 Carbohydrates
6.5 Miscellaneous
References
Index 347
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Add Functionalised N-Heterocyclic Carbene Complexes, N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can a, Functionalised N-Heterocyclic Carbene Complexes to the inventory that you are selling on WonderClubX
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Add Functionalised N-Heterocyclic Carbene Complexes, N-heterocyclic carbenes (NHCs) have found increasing use as reagents for a range of organic transformations and in asymmetric organocatalysis. The performance of these molecules can be improved and tuned by functionalisation. Functionalised carbenes can a, Functionalised N-Heterocyclic Carbene Complexes to your collection on WonderClub |