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Transition Metal Catalysis in Macromolecular Design Book

Transition Metal Catalysis in Macromolecular Design
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Transition Metal Catalysis in Macromolecular Design, Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple u, Transition Metal Catalysis in Macromolecular Design
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  • Transition Metal Catalysis in Macromolecular Design
  • Written by author Lisa Saunders Boffa, Bruce M. Novak
  • Published by American Chemical Society, 2000/11/30
  • Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. Advanced Catalysis demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple u
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Preface ix
1. The Organometallic Polymerization of (Meth)acrylates: An Overview 1
New Chain-Building Mechanisms
2. New Applications of "Carbonylbis(triphenylphosphine)ruthenium" Catalysis in Polymer Synthesis 24
3. Transition Metal-Catalyzed Alkyne Cycloaddition Polymerization 38
4. Synthetic Control over Substituent Location on Carbon-Chain Polymers Using Ring-Opening Polymerization of Small Cycloalkanes 59
5. Nucleophilic Polymerization of Methyl Methacrylate Activated by a Bronsted Acid 77
Polymer Modification Using Transition Metals
6. Modification of Polybutadiene by Transition Metal Catalysts: Hydroacylation of Polybutadiene 94
7. Metallocene Catalysts Used for the Hydrogenation of Polystyrene-b-Polybutadiene-b-Polystyrene Block Copolymers 108
8. E-Glass Fiber Supported Hydrosilation Catalysts 127
Olefin/Alkyne Addition Polymerization
9. New Catalysts for Polymerizations of Substituted Acetylenes 146
10. Addition Polymerization of Norbornene: Catalysis of Monocyclopentadienyltitanium Compounds Activated with Methylaluminoxane 165
11. Transfer and Isomerization Reactions in Propylene Polymerization with the Isospecific, Highly Regiospecific rac-Me[subscript 2]C(3-t-Bu-1-Ind)[subscript 2]ZrCl[subscript 2]/MAO Catalyst 174
Controlled Radical Polymerization
12. Living Radical Polymerization of Acrylates with Rhenium(V)-Based Initiating Systems: ReO[subscript 2]I(PPh[subscript 3])[subscript 2]/Alkyl Iodide 196
13. The Effect of Ligands on Copper-Mediated Atom Transfer Radical Polymerization 207
14. Structural Chemistry and Polymerization Activity of Copper(I) Atom Transfer Radical Polymerization Catalysts 224
15. Atom Transfer Polymerization Mediated by Solid-Supported Catalysts 236
16. Mechanistic Aspects of Catalytic Chain Transfer Polymerization 254
Indexes
Author Index 275
Subject Index 276


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Transition Metal Catalysis in Macromolecular Design, 
Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. <em>Advanced Catalysis</em> demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple u, Transition Metal Catalysis in Macromolecular Design

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Transition Metal Catalysis in Macromolecular Design, 
Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. <em>Advanced Catalysis</em> demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple u, Transition Metal Catalysis in Macromolecular Design

Transition Metal Catalysis in Macromolecular Design

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Transition Metal Catalysis in Macromolecular Design, 
Metal-mediated polymerization is fast becoming an essential tool for the fine control of macromolecular architecture. <em>Advanced Catalysis</em> demonstrates how the field of transition metal-catalyzed polymer syntheses has moved beyond the simple u, Transition Metal Catalysis in Macromolecular Design

Transition Metal Catalysis in Macromolecular Design

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