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Series Foreword | ||
Preface | ||
Acknowledgments | ||
Abbreviations | ||
1 | Introduction | 1 |
2 | Preparation of Nitro Compounds | 3 |
2.1 | Nitration of Hydrocarbons | 3 |
2.2 | Synthesis of Nitro Compounds by Oxidation | 20 |
3 | The Nitro-Aldol (Henry) Reaction | 30 |
3.1 | Preparation of [beta]-Nitro Alcohols | 31 |
3.2 | Derivatives from [beta]-Nitro Alcohols | 38 |
3.3 | Stereoselective Henry Reactions and Applications to Organic Synthesis | 51 |
4 | Michael Addition | 70 |
4.1 | Addition to Nitroalkenes | 70 |
4.2 | Addition and Elimination Reaction of [beta]-Heterosubsituted Nitroalkenes | 100 |
4.3 | Michael Addition of Nitroalkanes | 103 |
4.4 | Asymmetric Michael Addition | 115 |
5 | Alkylation, Acylation, and Halogenation of Nitro Compounds | 126 |
5.1 | Alkylation of Nitro Compounds | 126 |
5.2 | Acylation of Nitroalkanes | 128 |
5.3 | Ring Cleavage of Cyclic [alpha]-Nitro Ketones (Retro-Acylation) | 131 |
5.4 | Alkylation of Nitro Compounds via Alkyl Radicals | 133 |
5.5 | Alkylation of Nitro Compounds Using Transition Metal Catalysis | 138 |
5.6 | Arylation of Nitro Compounds | 147 |
5.7 | Introduction of Heteroatoms to Nitroalkanes | 149 |
6 | Conversion of Nitro Compounds into Other Compounds | 159 |
6.1 | Nef Reaction (Aldehydes, Ketones, and Carboxylic Acids) | 159 |
6.2 | Nitrile Oxides and Nitriles | 167 |
6.3 | Reduction of Nitro Compounds into Amines | 170 |
7 | Substitution and Elimination of NO[subscript 2] in R-NO[subscript 2] | 182 |
7.1 | R-Nu from R-NO[subscript 2] | 182 |
7.2 | R-H from R-NO[subscript 2] | 193 |
7.3 | Alkenes from R-NO[subscript 2] | 214 |
8 | Cycloaddition Chemistry of Nitro Compounds | 231 |
8.1 | Diels-Alder Reactions | 231 |
8.2 | 1,3-Dipolar Cycloaddition | 249 |
8.3 | Nitroalkenes as Heterodienes in Tandem [4+2]/[3+2] Cycloaddition | 274 |
9 | Nucleophilic Aromatic Displacement | 302 |
9.1 | S[subscript N]Ar | 302 |
9.2 | Nucleophilic Aromatic Substitution of Hydrogen (NASH) | 309 |
10 | Synthesis of Heterocyclic Compounds | 325 |
10.1 | Pyrroles | 325 |
10.2 | Synthesis of Indoles | 338 |
10.3 | Synthesis of Other Nitrogen Heterocycles | 346 |
Index | 365 |
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Add The Nitro Group in Organic Synthesis, Nitro compounds (compounds containing NO2) are useful intermediates for the synthesis of natural products and other complex organic molecules. Historically used in the synthesis of explosives, they are increasingly important to the modern pharmaceutical, , The Nitro Group in Organic Synthesis to the inventory that you are selling on WonderClubX
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Add The Nitro Group in Organic Synthesis, Nitro compounds (compounds containing NO2) are useful intermediates for the synthesis of natural products and other complex organic molecules. Historically used in the synthesis of explosives, they are increasingly important to the modern pharmaceutical, , The Nitro Group in Organic Synthesis to your collection on WonderClub |