Isotope Effects in Gas-Phase Chemistry Book

	Preface
1	Isotope Effects in Gas-Phase Chemical Reactions and Photodissociation Processes: Overview	1
	Theoretical Studies of Isotope Effects in Chemical Reactions
2	Variational Transition-State Theory with Multidimensional, Semiclassical, Ground-State Transmission Coefficients: Applications to Secondary Deuterium Kinetic Isotope Effects in Reactions Involving Methane and Chloromethane
3	HN[subscript 2] and DN[subscript 2] Resonance Spectra: Scattering and Stabilization Calculations	37
4	Isotope Effects in Addition Reactions of Importance in Combustion: Theoretical Studies of the Reactions CH + H[subscript 2] [actual symbol not reproducible] CH[subscript 3] [actual symbol not reproducible] CH[subscript 2] + H	48
	Experimental Studies of Isotope Effects in Reactions of Neutral Systems
5	Hydrogen Isotope Effects in Chemical Reactions and Photodissociations	66
6	Isotope Effects at High Temperatures Studied by the Flash or Laser Photolysis-Shock Tube Technique	80
7	Deuterium Substitution Used as a Tool for Investigating Mechanisms of Gas-Phase Free-Radical Reactions	94
8	Kinetic Isotope Effects in Gas-Phase Muonium Reactions	111
9	Mass-Independent Isotopic Fractionations and Their Applications	138
10	Heavy Ozone Anomaly: Evidence for a Mysterious Mechanism	155
11	Isotopic Study of the Mechanism of Ozone Formation	167
12	Negative-Ion Formation by Rydberg Electron Transfer: Isotope-Dependent Rate Constants	181
	Experimental Studies of Isotope Effects in Reactions of Ionic Systems
13	Isotope Effects in the Reactions of Atomic Ions with H[subscript 2], D[subscript 2], and HD	194
14	Non-Mass-Dependent Isotope Effects in the Formation of O[subscript 4][superscript +]: Evidence for a Symmetry Restriction	210
15	Temperature, Kinetic Energy, and Rotational Temperature Effects in Four Reactions Involving Isotopes	225
16	Isotope-Exchange Reactions Within Gas-Phase Protonated Cluster Ions	246
	Isotope Effects in Photodissociation Processes
17	Mechanisms for Isotopic Enrichment in Photochemical Reactions	264
18	State-Selected Dissociation of trans-HONO[actual symbol not reproducible] and DONO[actual symbol not reproducible]: Effect of Intramolecular Vibrational Dynamics on Fragmentation Rate, Stereochemistry, and Product Energy Distribution	279
19	Isotopic Dependence of the Methyl-Radical Rydberg 3 s Predissociation Dynamics	297
20	Laser-Stimulated Selective Reactions and Synthesis of Isotopomers: New Strategies from Diatomic to Organometallic Molecules
21	Multiphoton Ionization Dynamics Within (CH[subscript 3]OH)[subscript n]Cr(CO)[subscript 6] van der Waals Clusters: Isotope Effects in Intracluster Energy Transfer	335
	Applications of Isotope Effects
22	Deuterium Fractionation in Interstellar Space	358
23	Deuterium in the Solar System	369
24	Kinetic Isotope Effects and Their Use in Studying Atmospheric Trace Species: Case Study, CH[subscript 4] + OH	390
25	Key Sulfur-Containing Compounds in the Atmosphere and Ocean: Determination by Gas Chromatography-Mass Spectrometry and Isotopically Labeled Internal Standards	409
	Author Index	425
	Affiliation Index	426
	Subject Index	426