Controlled Radical Polymerization, Vol. 685 Book

	Preface
1	Overview: Fundamentals of Controlled/Living Radical Polymerization	2
2	Radical Addition to Alkenes: A Theoretical Perspective	31
3	Factors Influencing the Addition of Radicals to Alkenes	50
4	Cascade Radical Reactions in Organic Synthesis: An Overview	62
5	Selective Product Formation with Organometallic Radicals of Nickel and Zinc	72
6	Pulsed Laser Experiments Directed Toward the Detailed Study of Free-Radical Polmerizations	84
7	Termination Rate Coefficients from Molecular Weight Distributions	104
8	The Measurement and Meaning of Radical Reactivity Ratios	120
9	Electron Spin Resonance Studies of Radical Polymerization	145
10	The Stable Free-Radical Polymerization Process: Role of Excess Nitroxide	170
11	Mechanism and Kinetics of Nitroxide-Controlled Free-Radical Polymerization	180
12	Styrene Polymerization Mediated by Five-Membered Cyclic Nitroxides	200
13	Nitroxide-Mediated Radical Polymerization: End-Group Analysis	214
14	Controlled/Living Free-Radical Polymerization of Styrene and n-Butyl Acrylate in the Presence of a Novel Asymmetric Nitroxyl Radical	225
15	Nitroxide-Mediated Controlled Radical Polymerization: Toward Control of Molar Mass	236
16	Mechanistic Aspects of Atom Transfer Radical Polymerization	258
17	Atom Transfer Radical Polymerization of Methyl Methacrylate: Effect of Phenols	284
18	Living Radical Polymerization Mediated by Transition Metals: Recent Advances	296
19	Control of Radical Polymerizations by Metalloradicals	305
20	Photochemical Polymerizations Initiated and Mediated by Soluble Organocobalt Compounds	316
21	Controlled-Growth Free-Radical Polymerization of Methacrylate Esters: Reversible Chain Transfer versus Reversible Termination	332
22	Free-Radical Synthesis of Functional Polymers Involving Addition-Fragmentation Reactions	362
23	Applications of Barton Esters in Polymer Synthesis and Modification via Free-Radical Processes	377
24	How to Make Polymer Chains of Various Shapes, Compositions, and Functionalities by Atom Transfer Radical Polymerization	396
25	Controlled Radical Polymerization Methods for the Synthesis of Nonionic Surfactants for CO[subscript 2]	418
26	Design Strategies for Branched and Highly Branched Macromolecular Architectures Using Nitroxide-Mediated Living Free-Radical Procedures	433
27	Stereochemical Control of Free-Radical Polymerization of Vinyl Monomers	451
	Indexes	465