Analytical and Physical Electrochemistry Book

Preface Preface to the Original French Version ELECTROCHEMICAL POTENTIAL Electrochemical Potential of Ions Electrochemical Potential of Electrons ELECTROCHEMICAL EQUILIBRIA Redox Reactions at Metallic Electrodes Cells and Accumulators Pourbaix Diagrams Electrochemical Equilibria at the Interface Between Two Electrolytes Analytical Applications to Potentiometry Ion Exchange Membranes Appendix: The Respiratory Chain ELECTROLYTE SOLUTIONS Liquids Thermodynamic Aspects of Solvation Structural Aspects of Ionic Solvation Ion-Ion Interactions Ion Pairs Computational Methods Appendix TRANSPORT IN SOLUTION Transport in Electrolyte Solutions Conductivity of Electrolyte Solutions Influence of Concentration on Conductivity Dielectric Friction Thermodynamics of Irreversible Systems Statistical Aspects of Diffusion Appendix: Elements of Fluid Mechanics ELECTRIFIED INTERFACES Interfacial Tension Interfacial Thermodynamics Thermodynamics of Electrified Interfaces Spatial Distribution of Polarization Charges Structure of Electrochemical Interfaces ELECTROKINETIC PHENOMENA AND ELECTROCHEMICAL SEPARATION METHODS Electrokinetic Phenomena Capillary Electrophoresis Electrophoretic Methods of Analytical Separation Electrophoretic Separation of Biopolymers Ion Chromatography Industrial Methods of Electrochemical Separation STEADY STATE AMPEROMETRY Electrochemical Kinetics Current Controlled by the Kinetics of the Redox Reactions Reversible Systems: Current Limited by Diffusion Electrodes with a Diffusion Layer of Controlled Thickness Quasi-Reversible Systems: Current Limited by Kinetics and Diffusion Irreversible Systems: Current Limited by Kinetics and Diffusion Quasi-Reversible Systems: Current Limited by Diffusion, Migration, and Kinetics Experimental Aspects of Amperometry PULSE VOLTAMMETRY Chronoamperometry Following a Potential Step Polarography Square Wave Voltammetry Stripping Voltammetry Thin Layer Voltammetry Amperometric Detectors for Chromatography ELECTROCHEMICAL IMPEDANCE Transfer Function Elementary Circuits Impedance of an Electrochemical System AC Voltammetry CYCLIC VOLTAMMETRY Electrochemically Reversible Reactions with Semi-Infinite Linear Diffusion Influence of the Kinetics EC Reactions Electron Transfer at Liquid/Liquid Interfaces Assisted Ion Transfer at Liquid/Liquid Interfaces Surface Reactions Hemi-Spherical Diffusion Voltabsorptometry Semi-Integration ANNEX A: VECTOR ANALYSIS Coordinate Systems Circulation of the Field Vector The Vector Gradient Flux of the Field Vector The Green-Ostrogradski Theorem ANNEX B: WORK FUNCTIONS AND STANDARD REDOX POTENTIALS SYMBOLS INDEX