Molecular Theory of Water and Aqueous Solutions, Part 1: Understanding Water Book

List of Abbreviations

1 Survey of the Properties of Water 1

2 Theoretical Approaches to the Study of Liquid Water 96

3 Water with One Simple Solute 280

4 Water with Two Solute Molecules; Hydrophobic Hydrophilic Phenomena 411

Appendix A The Tetrahedral Geometry 564

Appendix B Calculation of the Residual Entropy of Water 565

Appendix C The Kirkwood-Buff Integrals for an Ideal Gas 568

Appendix D The Equivalence Between the One-Component and the Mixture-Model Views of the Same System 570

Appendix E The Generalized Euler Theorem 576

Appendix F Some Identities in the Mixture-Model Approach 580

Appendix G The Statistical Mechanical Expression for the Solvation Gibbs Energy of Hard Spheres and the Work of Cavity Formation 584

Appendix H The Solubility of a Simple Solute in Water and Structural Changes Induced in the Solvent 586

Appendix I An Estimate of the Strength of Hydrophilic Interaction at R = 4.5 A 591

Appendix J Calculated Data on HoI Interactions 596

Appendix K Experimental Evidence for the Entropy-Enthalpy Compensation 598

Appendix L Solutions to Selected Exercises 600

References 611

Index 625