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Ionic Liquids in Synthesis, 2 Volume Set Book

Ionic Liquids in Synthesis, 2 Volume Set
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  • Ionic Liquids in Synthesis, 2 Volume Set
  • Written by author Peter Wasserscheid
  • Published by Wiley, John & Sons, Incorporated, December 2007
  • Synthetic chemistry has been dominated by reactions in volatile solvents for a long time. Since some of these eventually happened to be toxic or otherwise environmentally damaging, the introduction of cleaner technologies has become a major
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Authors

Preface
Contributors
1Introduction1
2Synthesis and Purification of Ionic Liquids7
2.1Synthesis of Ionic Liquids7
2.2Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production21
2.3Synthesis of Task-specific Ionic Liquids33
3Physicochemical Properties of Ionic Liquids41
3.1Melting Points and Phase Diagrams41
3.2Viscosity and Density of Ionic Liquids56
3.3Solubility and Solvation in Ionic Liquids68
3.4Gas Solubilities in Ionic Liquids81
3.5Polarity94
3.6Electrochemical Properties of Ionic Liquids103
4Molecular Structure and Dynamics127
4.1Order in the Liquid State and Structure127
4.2Quantum Mechanical methods for Structure Elucidation152
4.3Molecular Dynamics Simulation Studies157
4.4Translational Diffusion162
4.5Molecular Reorientational Dynamics168
5Organic Synthesis174
5.1Stoichiometric Organic Reactions and Acid-Catalyzed Reactions in Ionic Liquids174
5.2Transition Metal Catalysis in Ionic Liquids213
5.3Ionic Liquids in Multiphasic Reactions258
5.4Multiphasic Catalysis with Ionic Liquids in Combination with Compressed CO[subscript 2]281
6Inorganic Synthesis289
6.1Directed Inorganic and Organometallic Synthesis289
6.2Making of Inorganic Materials by Electrochemical Methods294
7Polymer Synthesis in Ionic Liquids319
7.1Introduction319
7.2Acid-catalyzed Cationic Polymerization and Oligomerization320
7.3Free Radical Polymerization324
7.4Transition Metal-catalyzed Polymerization326
7.5Preparation of Conductive Polymers331
7.6Conclusions332
8Biocatalytic Reactions in Ionic Liquids336
8.1Introduction336
8.2Biocatalytic Reactions and their Special Needs336
8.3Examples of Biocatalytic Reactions in Ionic Liquids339
8.4Conclusions and Outlook345
9Outlook348
Index356


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