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Preface | ||
Contributors | ||
1 | Introduction | 1 |
2 | Synthesis and Purification of Ionic Liquids | 7 |
2.1 | Synthesis of Ionic Liquids | 7 |
2.2 | Quality Aspects and Other Questions Related to Commercial Ionic Liquid Production | 21 |
2.3 | Synthesis of Task-specific Ionic Liquids | 33 |
3 | Physicochemical Properties of Ionic Liquids | 41 |
3.1 | Melting Points and Phase Diagrams | 41 |
3.2 | Viscosity and Density of Ionic Liquids | 56 |
3.3 | Solubility and Solvation in Ionic Liquids | 68 |
3.4 | Gas Solubilities in Ionic Liquids | 81 |
3.5 | Polarity | 94 |
3.6 | Electrochemical Properties of Ionic Liquids | 103 |
4 | Molecular Structure and Dynamics | 127 |
4.1 | Order in the Liquid State and Structure | 127 |
4.2 | Quantum Mechanical methods for Structure Elucidation | 152 |
4.3 | Molecular Dynamics Simulation Studies | 157 |
4.4 | Translational Diffusion | 162 |
4.5 | Molecular Reorientational Dynamics | 168 |
5 | Organic Synthesis | 174 |
5.1 | Stoichiometric Organic Reactions and Acid-Catalyzed Reactions in Ionic Liquids | 174 |
5.2 | Transition Metal Catalysis in Ionic Liquids | 213 |
5.3 | Ionic Liquids in Multiphasic Reactions | 258 |
5.4 | Multiphasic Catalysis with Ionic Liquids in Combination with Compressed CO[subscript 2] | 281 |
6 | Inorganic Synthesis | 289 |
6.1 | Directed Inorganic and Organometallic Synthesis | 289 |
6.2 | Making of Inorganic Materials by Electrochemical Methods | 294 |
7 | Polymer Synthesis in Ionic Liquids | 319 |
7.1 | Introduction | 319 |
7.2 | Acid-catalyzed Cationic Polymerization and Oligomerization | 320 |
7.3 | Free Radical Polymerization | 324 |
7.4 | Transition Metal-catalyzed Polymerization | 326 |
7.5 | Preparation of Conductive Polymers | 331 |
7.6 | Conclusions | 332 |
8 | Biocatalytic Reactions in Ionic Liquids | 336 |
8.1 | Introduction | 336 |
8.2 | Biocatalytic Reactions and their Special Needs | 336 |
8.3 | Examples of Biocatalytic Reactions in Ionic Liquids | 339 |
8.4 | Conclusions and Outlook | 345 |
9 | Outlook | 348 |
Index | 356 |
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