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1 | Introduction and Historical Background | 1 |
2 | Terpenoid Chemistry | 19 |
Introduction - Nomenclature | 19 | |
Acyclic Monoterpenes | 24 | |
Monocyclic Monoterpenes | 36 | |
Bicyclic Monoterpenes | 63 | |
3 | Industrial Syntheses Starting from [alpha]- and [beta]-Pinene | 85 |
Acid-Catalized Reactions | 85 | |
Pyrolysis Reactions of the Pinenes | 92 | |
Hydroperoxidation Reactions | 99 | |
4 | Total Synthesis of Aliphatic Terpenoids of Industrial Importance | 109 |
Ethynylation reactions | 111 | |
Methods for the Synthesis of Methylheptenone | 120 | |
Industrial Chemistry of Dehydrolinalool | 125 | |
Synthesis of Terpenoids | 136 | |
5 | Biogenesis of Natural Substances | 145 |
Some Aspects of Enzymology and Biochemistry | 150 | |
Biosynthetic Mechanisms Leading to Terpenoids | 173 | |
6 | The Chemistry of Sesquiterpenes and of Some Macrocyclic Diterpenes | 193 |
Cyclizations and Interconversions in the Sesquiterpene Series | 193 | |
Detailed Study of Some Syntheses of Sesquiterpenes of Major Interest | 242 | |
The Chemistry of Diterpenes with 14-Membered Rings | 281 | |
7 | Substances with a Musk Odor | 289 |
Methods of Synthesis of Macrocyclic Ketones | 292 | |
Methods of Synthesis of Macrocyclic Lactones | 325 | |
Aromatic musks | 333 | |
Appendix 1. The Concept of Prochirality | 359 | |
Appendix 2. The Wittig Reaction | 365 | |
Appendix 3. The Chemistry of Enol Ethers | 385 | |
Appendix 4. Functionalization of Unactivated Carbon Atoms | 401 | |
Appendix 5. Methods for Identifying Natural and Synthetic Organic Compounds | 417 | |
Appendix 6. Summary of Some Physico-Chemical Methods Used in the Analysis of Natural Odorant Products | 425 | |
Bibliography | 433 | |
Index | 451 |
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