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Organic Structures from Spectra Book

Organic Structures from Spectra
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Organic Structures from Spectra, Organic Structures from Spectra, Fourth Edition consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student's under, Organic Structures from Spectra
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  • Organic Structures from Spectra
  • Written by author L. D. Field
  • Published by Wiley, John & Sons, Incorporated, 2/18/2013
  • Organic Structures from Spectra, Fourth Edition consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student's under
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Authors

Preface
List of Tables
List of Figures
1 Introduction 1
1.1 General Principles of Absorption Spectroscopy 1
1.2 Chromophores 3
1.3 Connectivity 3
1.4 Sensitivity 4
1.5 Practical Considerations 4
2 Ultraviolet (UV) Spectroscopy 6
2.1 Basic Instrumentation 6
2.2 The Nature of Ultraviolet Spectroscopy 7
2.3 Quantitative Aspects of Ultraviolet Spectroscopy 7
2.4 Classification of UV Absorption Bands 8
2.5 Special Terms in Ultraviolet Spectroscopy 9
2.6 Important UV Chromophores 9
2.7 The Effect of Solvents 13
3 Infrared (IR) Spectroscopy 14
3.1 Absorption Range and the Nature of IR Absorption 14
3.2 Experimental Aspects of Infrared Spectroscopy 15
3.3 General Features of Infrared Spectra 15
3.4 Important IR Chromophores 16
4 Mass Spectrometry 20
4.1 Ionization Processes 20
4.2 Instrumentation 21
4.3 Mass Spectral Data 22
4.4 Representation of Fragmentation Processes 27
4.5 Factors Governing Fragmentation Processes 27
4.6 Examples of Common Types of Fragmentation 27
5 Nuclear Magnetic Resonance (NMR) Spectroscopy 32
5.1 The Physics of Nuclear Spins and NMR Instruments 32
5.2 Continuous Wave (CW) NMR Spectroscopy 36
5.3 Fourier-Transform (FT) NMR Spectroscopy 37
5.4 Chemical Shifts in [superscript 1]H NMR Spectroscopy 39
5.5 Spin-Spin Coupling in [superscript 1]H NMR Spectroscopy 46
5.6 Analysis of [superscript 1]H NMR Spectra 50
5.7 Rules for Spectral Analysis 52
6 [superscript 13]C NMR Spectroscopy 62
6.1 Coupling and Decoupling in [superscript 13]C NMR Spectra 62
6.2 Determining [superscript 13]C Signal Multiplicity Using DEPT 64
6.3 Shielding and Characteristic Chemical Shifts in [superscript 13]C NMR Spectra 67
7 Miscellaneous Topics 71
7.1 Dynamic Processes in NMR - The NMR Time-Scale 71
7.2 The Effect of Chirality 74
7.3 The Nuclear Overhauser Effect (NOE) 75
7.4 Two Dimensional NMR 76
7.5 The NMR Spectra Of "Other Nuclei" 78
7.6 Solvent - Induced Shifts 79
8 Determining the Structure of Organic Molecules from Spectra 80
9 Problems 83
Appendix 361
Index 367


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Organic Structures from Spectra, <i>Organic Structures from Spectra, Fourth Edition</i> consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student's under, Organic Structures from Spectra

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Organic Structures from Spectra, <i>Organic Structures from Spectra, Fourth Edition</i> consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student's under, Organic Structures from Spectra

Organic Structures from Spectra

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Organic Structures from Spectra, <i>Organic Structures from Spectra, Fourth Edition</i> consists of a carefully selected set of over 300 structural problems involving the use of all the major spectroscopic techniques. The problems are graded to develop and consolidate the student's under, Organic Structures from Spectra

Organic Structures from Spectra

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