Inorganic Reactions and Methods: The Formation of Bonds to C, Si, Ge, Sn, Pb Book

How to Use this Book
Preface to the Series
Editorial Consultants to the Series
Contributors to Volume 11
5. The Formation of Bonds to Elements of Group IVB (C, Si, Ge, Sn, Pb) (Part 3)
5.5. Formation of Bonds between Elements of Groups IVB (C, Si, Ge, Sn, Pb) and IA (Li, Na, K, Rb, Cs, Fr)
5.5.1. Introduction
5.5.2 Carbon-Lithium Bonds
5.5.2.1 from the Elements.
5.5.2.2. from Lithium and its Alloys
5.5.2.2.1. with Organic Halides.
5.5.2.2.2. with Organomercurials.
5.5.2.2.3. with Adducts of Conjugated Hydrocarbons in Donor Solvents.
5.5.2.2.4. with Acidic Hydrocarbons Evolving H2.
5.5.2.2.5 with Ethers, Amines, Sulfides and Phosphines Cleaving the Carbon-Element Bonds.
5.5.2.3. from Other Organolithiums
5.5.2.3.1. by Metal-Metal Exchange with Less Active Organometallics.
5.5.2.3.2. by Proton-Metal Exchange with Acidic C--H Bonds.
5.5.2.3.3. by Halogen-Lithium Exchange with Organic Halides.
5.5.2.3.4. by Addition of Organolithiums to Olefins or Acetylenes.
5.5.2.3.5. by Action of Lithium Arene Radical Anions and Dianions.
5.5.3. Carbon-Group-IA Bonds
5.5.3.1. from the Elements
5.5.3.1.1. Giving Na Carbides.
5.5.3.1.2. Giving K, Rb and Cs Carbides.
5.5.3.2. from the Group-IA Metals and Their Alloys
5.5.3.2.1. with Organic Halides.
5.5.3.2.2. with Ethers.
5.5.3.2.3. with Organomercurials.
5.5.3.2.4. with Adducts of Conjugated Hydrocarbons in Donor Solvents.
5.5.3.2.5. with Acidic Hydrocarbons Evolving H2.
5.5.3.2.6. by Cleavage of Carbon-Carbon Bonds.
5.5.3.3. from Other Group-IA Organometallics of the Same Metal
5.5.3.3.1. by Proton-Metal Exchange with Acidic C--H Bonds.
5.5.3.3.2. byMetal-Metal Exchange with Less Active Organometallics.
5.5.3.3.3. by Addition to Olefins and Acetylenes.
5.5.4. Silicon-Group-IA Bonds
5.5.4.1. from the Elements.
5.5.4.2. from Organodi- and Organopolysilanes
5.5.4.2.1. with Alkali Metals.
5.5.4.2.2. with Anionic Reagents.
5.5.4.3. from Organohalosilanes with Alkali Metals.
5.5.4.4. from Organosilicon Hydrides with Alkali Metals and Metal Hydrides.
5.5.4.5. from Tetraorganosilanes with Alkali Metals.
5.5.4.6. from Silylmercurials.
5.5.4.7. from Exchange.
5.5.5. Germanium-Group-IA Bonds
5.5.5.1. from the Elements.
5.5.5.2. from Organodigermanes
5.5.5.2.1. with Alkali Metals.
5.5.5.2.2. with Alkali-Metal Alkoxides and Organolithiums.
5.5.5.3. from Organohalogermanes with Alkali Metals.
5.5.5.4. from Organogermanium Hydrides with Alkali Metals and Derivatives.
5.5.5.5. from Tetraorganogermanes with Alkali Metals.
5.5.5.6. from Germy-Mercury and -Thallium with Alkali Metals.
5.5.5.7. from Exchange and/or Ge(II) Derivatives.
5.5.6. Tin-Group-IA Bonds
5.5.6.1. from the Elements
5.5.6.1.1. Lithium.
5.5.6.1.2. Sodium.
5.5.6.1.3. Potassium.
5.5.6.1.4. Rubidium.
5.5.6.1.5. Cesium.
5.5.6.2. from Organodistannanes with Alkali Metals
5.5.6.2.1. Lithium.
5.5.6.2.2. Sodium.
5.5.6.2.3. Potassium.
5.5.6.3. from Organotin Halides with Alkali Metals
5.5.6.3.1. Lithium.
5.5.6.3.2. Sodium.
5.5.6.3.3. Potassium.
5.5.6.4. from Organotin Hydrides with Alkali Metals.
5.5.6.5. from Tetraorganotins with Alkali Metals.
5.5.6.6. from Tin(II) Compounds with Organoalkali Reagents.
5.5.7. Lead-Group-IA Bonds
5.5.7.1. in Alloys and Intermetallics
5.5.7.1.1. from the Elements.
5.5.7.1.2. by Reduction.
5.5.7.1.3. by Electrolysis.
5.5.7.2. from Hexaorganodiplumbanes.
5.5.7.2.1. with Alkali Metals.
5.5.7.2.2. with Organoalkali Reagents.
5.5.7.3. from Tetraorganoleads with Alkali Metals.
5.5.7.4. from Organolead Halides with Alkali Metals.
5.5.7.5. from Lead(II) Compounds with Organoalkali Reagents.
5.5.7.6. by Miscellaneous Routes.
5.6. Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group IIB (Cu, Ag, Au)
5.6.1. Introduction
5.6.2. from the Elements.
5.6.3. from the Group-IB Metals and Alloys.
5.6.4. from the Metal Salts
5.6.4.1. by Metal-Metal Exchange with Another Organometallic.
5.6.4.2. by Metal-Halogen Exchange.
5.6.4.3. by Metallation.
5.6.4.4. by Insertion.
5.6.4.5. by Addition, Decarboxylation.
5.6.4.6. by Forming Adducts with Unsaturated Hydrocarbons.
5.6.5. From the Metal-Phosphine Complexes
5.6.5.1. with Triaryl Group IV-Alkali-Metal Derivatives.
5.6.5.2. by Insertion.
5.6.5.3. by Transmetallation.
5.6.5.4. by Metal-Halide Exchange.
5.7 Formation of Bonds between Elements of Group IVB (C, Si, Ge, Sn, Pb) and Group lib (Zn, Cd, Hg)
5.7.1. Introduction
5.7.2. Carbon-Group-IIB Bonds
5.7.2.1. from the Elements.
5.7.2.2. from the Group-IIB Metals and Alloys
5.7.2.2.1. with Organic Halides and Sulfates.
5.7.2.2.2. with Organomercurials.
5.7.2.2.3. with Aryldiazonium Salts.
5.7.2.3. from Metal Salts
5.7.2.3.1. with Organometallics.
5.7.2.3.2. by Redistribution with the Organometallics of the Same Metal.
5.7.2.3.3. by Addition to Olefins and Acetylenes or Cyclopropanes by Ring Opening.
5.7.2.3.4. with Acidic Hydrocarbons.
5.7.2.3.5. with Diazoalkanes.
5.7.2.3.6. with Diazonium Salts.
5.7.2.3.7. with Organosulfinic, Organosulfonic and Organoboronic Acid Derivatives.
5.7.2.4. from Other Group-IIB Organometallics of the Same Metal
5.7.2.4.1. by Proton-Metal Exchange with Acidic Hydrocarbons.
5.7.2.4.2. by Olefin Insertion.
5.7.2.4.3. by Metal-Metal Exchange with Other Organometallics.
5.7.3. Silicon-Group-IIB Bonds
5.7.3.1. from Silyl-Alkali-Metal Reagents with Group-IIB Halides and Organohalides.
5.7.3.2. from Organohalosilanes with Na or Al Amalgam.
5.7.3.3. from Organosilicon Hydrides with Zn, Cd and Hg Dialkyls.
5.7.3.4. from Silylcadmiums and -Thalliums with Hg Metal.
5.7.3.5. from Redistribution and Related Reactions.
5.7.4. Ge-Group-IIB Bonds
5.7.4.1. from Germyl-Alkali-Metal Reagents with Group-IIB Halides and Organohalides.
5.7.4.2. from Organogermanium Hydrides with Zn, Cd and Hg Dialkyls.
5.7.4.3. from Organohalogermanes with Na Amalgam.
5.7.4.4. from Germylcadmiums, -thalliums and -bismuths with Hg.
5.7.4.5. from Digermanes with Hg(II) Compounds.
5.7.4.6. from Germyl-Group-IIB Compounds by Redistribution.
5.7.4.7. from Silyl- or Germylmercurials and Ge(IV) Halides.
5.7.4.8. by Insertion of Germylenes into Hg--C or Hg--Ge Bonds.
5.7.5. Tin-Group-IIB Bonds
5.7.5.1. from the Elements
5.7.5.1.1. with Zn.
5.7.5.1.2. with Cd.
5.7.5.1.3. with Hg.
5.7.5.2. from Organotin Hydrides with Zn, Cd and Hg Dialkyls
5.7.5.2.2. with CD Alkyls.
5.7.5.2.3. with Hg Alkyls.
5.7.5.3. from Organotin Halides with Germylmercurials.
5.7.5.4. from Organotin Alkoxides with Silylmercurials.
5.7.6. Lead-Group-IIB Bonds
5.7.6.1. in Alloys and Intermetallics
5.7.6.1.1. from the Elements.
5.7.6.1.2. by Reduction.
5.7.6.1.3. by Electrolysis.
5.7.6.2. in Organolead-Group-IIB Compounds.