Controlled/Living Radical Polymerization: From Synthesis to Materials Book

Preface     xiii
Overview
Controlled/Living Radical Polymerization: State of the Art in 2005   Krzysztof Matyjaszewski     2
Atom Transfer Radical Polymerization: Mechanisms and Materials
Living Radical Polymerization Catalyzed with Hydrophilic and Thermosensitive Ruthenium(II) Complexes in Aqueous Media   Toshihide Yoshitani   Yasuhiro Watanabe   Tsuyoshi Ando   Masami Kamigaito   Mitsuo Sawamoto     14
Stereospecific Living Radical Polymerization   Masami Kamigaito   Kotaro Satoh   Decheng Wan   Yuya Sugiyama   Kazuhiko Koumura   Takuya Shibata   Yoshio Okamoto     26
Controlled Radical Polymerization of Vinyl Monomers Catalyzed by Ruthenium N-Heterocyclic Carbene Complexes   Sebastien Delfosse   Aurore Richel   Lionel Delaude   Albert Demonceau   Alfred F. Noels     40
Factors Determining the Performance of Copper-Based Atom Transfer Radical Polymerization Catalysts and Criteria for Rational Catalyst Selection   Nicolay V. Tsarevsky   Wei Tang   Samuel J. Brooks   Krzysztof Matyjaszewski     56
Magnetic Nanoparticle Supported Catalyst for Atom Transfer Radical Polymerization of Methyl Methacrylate   Shijie Ding   Maciej Radosz   Youqing Shen     71
Loss in Activity and Catalyst Recyclability in Batch and Continuous Supported Atom Transfer Radical Polymerization   Santiago Faucher   Shiping Zhu     85
Alkylated Linear Amine Ligands for Homogeneous Atom Transfer Radical Polymerization   Metin H. Acar   C. Remzi Becer   H. Alper Ondur   Sebnem Inceoglu     97
Electron Spin Resonance Study of Methacrylate Radicals Generated from Purified Oligomers Prepared by Atom Transfer Radical Polymerization   Atsushi Kajiwara     111
Ti-Catalyzed Living Radical Polymerization of Styrene Initiated by Epoxide Radical Ring Opening   Alexandru D. Asandei   Isaac W. Moran   Gobinda Saha   Yanhui Chen     125
Click Functionalization of Well-Defined Copolymers Prepared by Atom Transfer Radical Polymerization   Brent S. Sumerlin   Nicolay V. Tsarevsky   Haifeng Gao   Patricia Golas   Guillaume Louche   Robert Y. Lee   Krzysztof Matyjaszewski     140
Polymers with Pendant Allyl Ester Groups Prepared via Atom Transfer Radical Polymerization: Synthesis, Characterization, and Microstructuring of Thin Films   Rene Nagelsdiek   Petra Mela   Martina Mennicken   Helmut Keul   Martin Moller     153
Controlled Radical Polymerization of 1-Ethoxyethyl (Meth)acrylate: Novel Route for the Synthesis of Poly((meth)acrylic acid) Containing Polymer Structures   Wim Van Camp   Filip E. Du Prez     171
Novel Organo-Soluble or Water-Soluble Copolymers Containing DNA Nucleobases   Jean-Francois Lutz   Rainer Nehring   Sebastian Pfeifer     185
Conjugates of Polymers and Sequence-Defined Polypeptides via Controlled Radical Polymerization   Mattijs G. J. Ten Cate   Hans G. Borner     198
Synthesis and Characterization of Methacrylate-Type Glycopolymers with Branched Architectures   Sharmila Muthukrishnan   Hideharu Mori   Axel H. E. Muller     214
Acrylate-Based Block Copolymers Prepared by Atom Transfer Radical Polymerization as Matrices for Drug Delivery Applications   Robert E. Richard   Marlene Schwarz   Shrirang Ranade   A. Ken Chan   Krzysztof Matyjaszewski   Brent Sumerlin     234
Grafting Chromatographic Stationary Phase Substrates by Atom Transfer Radical Polymerization   Patrick McCarthy   Nicolay V. Tsarevsky   Lindsay Bombalski   Krzysztof Matyjaszewski   Christopher Pohl     252
Synthesis of Inorganic-Polymer Nanocomposites by Atom Transfer Radical Polymerization Using Initiators or Polymerizable Groups Attached to Transition Metals via Bidentate Ligands   Guido Kickelbick   Dieter Holzinger   Dieter Rutzinger   Sorin Ivanovici     269
Surface Modification of Inorganic Nanotubes by Atom Transfer Radical Polymerization   Yuan Gao   Deyue Yan     279
Advances in Nanostructured Carbons from Block Copolymers Prepared by Controlled Radical Polymerization Techniques   Tomasz Kowalewski   Chuanbing Tang   Michal Kruk   Bruno Dufour   Krzysztof Matyjaszewski     295
Nitroxide Mediated Polymerization and Other Stable Free Radical Polymerization
An Overview of the Emulsion Stable Free Radical Nanoprecipitation Polymerization Process   Andrea R. Szkurhan   Michael K. Georges     312
Crowded Phosphonylated Alkoxyamines with Low Dissociation Temperatures: A Milestone in Nitroxide-Mediated Polymerization   Florence Chauvin   Jean-Luc Couturier   Pierre-Emmanuel Dufils   Pierre Gerard   Didier Gigmes   Olivier Guerret   Yohann Guillaneuf   Sylvain R. A. Marque   Denis Bertin   Paul Tordo     326
Reactive Block Copolymers as Versatile Compatibilizers   Leticia Flores-Santos   Alfonso Gonzalez-Montiel   Enrique Saldivar-Guerra     342
Living Radical Polymerizations Mediated by Metallo Radical and Organo-Transition Metal Complexes   Bradford B. Wayland   Xuefeng Fu   Chi-How Peng   Zhi Lu   Michael Fryd     358
Cobalt-Mediated Radical Polymerization of Vinyl Acetate: A New Tool for Macromolecular Engineering   Antoine Debuigne   Christophe Detrembleur   Rayna Bryaskova   Jean-Raphael Caille   Robert Jerome     372
Borane-Mediated Control Radical Polymerization: Synthesis of Chain End Functionalized Fluoropolymers   T. C. Chung   H. Hong   Z. C. Zhang   Z. M. Wang     387
Reversible Addition Fragmentation Chain Transfer and Other Degenerative Transfer Processes
An Ab Initio Guide to Structure-Reactivity Trends in Reversible Addition Fragmentation Chain Transfer Polymerization   Elizabeth H. Krenske   Ekaterina I. Izgorodina   Michelle L. Coote     406
Tailoring Molecular Weight Distribution and Structure with Difunctional Reversible Addition Fragmentation Chain Transfer Agent. A Model Study   Geoffrey Johnston-Hall   Michael J. Monteiro     421
Progress in RAFT/MADIX Polymerization. Synthesis, Use, and Recovery of Chain Transfer Agents   Sebastien Perrier   Pittaya Takolpuckdee   Steven Brown   Thomas M. Legge   Debashish Roy   Murray R. Wood   Steven P. Rannard    David J. Duncalf     438
Pulsed-Laser Initiated Reversible Addition Fragmentation Chain Transfer Polymerization   M. Buback   T. Junkers   P. Vana     455
Tailor-Made Copolymers via Reversible Addition Fragmentation Chain Transfer the Fast Way   Richard Hoogenboom   Martin W. M. Fijten   Renzo M. Paulus   Ulrich S. Schubert     473
Obtaining Chain Length Dependent Termination Rate Coefficients via Thermally Initiated Reversible Addition Fragmentation Chain Transfer Experiments: Current Status and Future Challenges   Alexander Theis   Martina H. Stenzel   Thomas P. Davis   Christopher Barner-Kowollik     486
Reversible Addition Fragmentation Chain Transfer-Mediated Copolymerizations: The Challenge of Random Copolymer Blocks   Bert Klumperman   James B. McLeary   Eric T. A. van den Dungen   Willem-Jan Soer   Jelena S. Bozovic     501
RAFT Copolymerization and Its Application to the Synthesis of Novel Dispersants-Intercalants-Exfoliants for Polymer-Clay Nanocomposites: Some Interesting Results from RAFT (Co)polymerization   Graeme Moad   Guoxin Li   Rudolf Pfaendner   Almar Postma   Ezio Rizzardo   San Thang   Hendrik Wermter     514
Controlled Synthesis of Amino Acid-Based Polymers by Reversible Addition Fragmentation Chain Transfer Polymerization   Hideharu Mori   Kazuhiko Sutoh   Hideyuki Iwaya   Atsushi Nagai   Takeshi Endo     533
Applications of Telechelic Reversible Addition Fragmentation Chain Transfer Polymers   John Lai   Dave Egan   Raymond Hsu   Carole Lepilleur   Alex Lubnin   Anthony Pajerski   Ronald Shea     547
Various Strategies for the Chemical Transformation of Xanthate-Functional Chain Termini in MADIX Copolymers   Mathias Destarac   Chakib Kalai   Agnieszka Wilczewska   Laurence Petit   Eric Van Gramberen   Samir Z. Zard     564
Direct Synthetic Strategies to Hydrophilic Starlike Polymers by MADIX   Daniel Taton   Jean-Francois Baussard   Ludovic Dupayage   Yves Gnanou   Mathias Destarac   Catherine Mignaud   Claire Pitois     578
Germanium- and Tin-Catalyzed Living Radical Polymerizations of Styrene   Atsushi Goto   Hirokazu Zushi   Yungwan Kwak   Takeshi Fukuda     595
Living Radical Ab Initio Emulsion Polymerization of n-Butyl Acrylate by Reverse Iodine Transfer Polymerization   J. Tonnar   P. Lacroix-Desmazes   B. Boutevin      604
Indexes
Author Index     623
Subject Index     627