Fluorinated Synthons Book

1	Recent advances in perfluoroalkylation methodology	2
2	New nucleophilic fluoroalkylation chemistry	16
3	Fluoroform, fluoral, trifluoroacetic, and trifluoromethanesulfinic acids derivatives as new reagents for the introduction of polyfluorinated moieties	57
4	SF[subscript 5]-synthons : pathways to organic derivatives of SF[subscript 6]	87
5	Stereoselective synthesis of monofluoroalkenes using cross-coupling reactions	120
6	A new in situ room temperature approach to fluorinated vinylzinc reagents and fluorinated styrenes	135
7	Vinyl fluorides in cycloadditions	155
8	Asymmetric synthesis of monofluorinated compounds having the fluorine atom vicinal to [pi]-systems	173
9	A new aspect of fluoroalkylated acetylenes : synthesis and applications - hydrometallation and carbometallation	190
10	Functionalized fluorinated allenes	204
11	Regioexhaustive functionalizations : to miss an isomer means to miss a chance	218
12	Perfluoroketene dithioacetals : versatile building blocks toward trifluoromethyl heterocycles	232
13	Highly functionalized heterocycles and macrocycles from pentafluoropyridine	248
14	Synthetic methods for the preparation of ring-fluorinated heterocycles via intramolecular vinylic substitution of gem-difluoroalkenes	262
15	Selective anodic fluorination of heterocyclic compounds	276
16	Polyfluorinated binaphthol ligands in asymmetric catalysis	288
17	Selective fluorination of biologically important imidazoles and indoles	303
18	Functional group transformations at [alpha]-carbon to trifluoromethyl group	318
19	Use of trifluoroacetaldehyde ethyl hemiacetal in a simple and practical synthesis of [beta]-hydroxy-[beta]-trifluoromethylated ketones	342
20	Fluorinated synthon : asymmetric catalytic reactions	356
21	Industrial synthetic application of fluoral and 3,3-dichloro-1,1,1-trifluoroacetone as fluorinated synthons	368
22	Synthesis and utility of fluorinated acylsilanes	378
23	The role of fluorine-containing methyl groups toward diastereofacial selection	399
24	Reactions of unsaturated organometallic reagents on trifluoroacetaldimines	412
25	Optically active gem-difluorocyclopropanes : synthesis and application for novel molecular materials	430
26	General methods for the synthesis of difluoromethylphosphonates	440
27	Mg-promoted selective C-F bond cleavage : a general and efficient access to difluoroenol silyl ethers and their derivatives	455
28	Reactions of ethyl bromodifluoroacetate in the presence of copper powder	476
29	Fluorine-based crystal engineering	498
30	Haloperfluorocarbons : versatile tectons in halogen bonding based crystal engineering	514
31	Fluoro-[beta]-lactams as useful building blocks for the synthesis of fluorinated amino acids, dipeptides, and taxoids	544
32	Synthesis of fluorinated prolines and pyroglutamic acids	562
33	Synthesis and properties of new fluorinated peptidomimetics	572
34	Fluorinated [beta]-enamino esters as versatile synthetic intermediates : synthesis of fluorinated [beta]-amino acids and uracils	593
35	Using the potential of fluorine for peptide and protein modification	611