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Advances in Controlled/Living Radical Polymerization Book

Advances in Controlled/Living Radical Polymerization
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Advances in Controlled/Living Radical Polymerization, Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis, Advances in Controlled/Living Radical Polymerization
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  • Advances in Controlled/Living Radical Polymerization
  • Written by author K. Matyjaszewski, Division of Polymer Chemistry Staff American Chemical Society, Meeting Staff American Chemical Society, Krzysztof Matyjaszewski
  • Published by OUP USA, 2003/07/10
  • Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis
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Preface
1Controlled/Living Radical Polymerization: State of the Art in 20022
2Criteria for Livingness and Control in Nitroxide-Mediated and Related Radical Polymerizations10
3Mechanisms and Kinetics of Living Radical Polymerization: Absolute Comparison of Theory and Experiment24
4Termination Kinetics of Acrylate and Methacrylate Homo- and Copolymerizations42
5Lewis Acid-Catalyzed Tacticity Control during Radical Polymerization of (Meth)acrylamides59
6Propagation and Termination in Free Radical Polymerization of Styrene to High Conversion Investigated by Electron Spin Resonance Spectroscopy72
7Electron Spin Resonance Study of Conventional Radical Polymerization of tert-Butyl (Meth)acrylates Using Radical Precursors Prepared by Atom Transfer Radical Polymerization86
8Living Radical Polymerization with Designed Metal Complexes102
9Controlled Radical Polymerization Catalyzed by Ruthenium Complexes: Variations on Ru-Cp#
10Toward Structural and Mechanistic Understanding of Transition Metal-Catalyzed Atom Transfer Radical Processes130
11Mechanistic Aspects of Copper-Mediated Living Radical Polymerization148
12ESR Study and Radical Observation in Transition Metal-Mediated Polymerization: Unified View of Atom Transfer Radical Polymerization Mechanism161
13Peculiarities in Atom Transfer Radical Copolymerization180
14Atom Transfer Radical Polymerization of Methyl Methacrylate Utilizing an Automated Synthesizer193
15Asymmetric Atom Transfer Radical Polymerization: Enantiomer-Selective Cyclopolymerization of rac-2,4-Pentanediyl Dimethacrylate Using Chiral ATRP Initiator206
16Organic Acids Used as New Ligands for Atom Transfer Radical Polymerization221
17Novel Fluorinated Polymer Materials Based on 2,3,5,6-Tetrafluoro-4-methoxystyrene236
18Copper Removal in Atom Transfer Radical Polymerization250
19Synthesis and Properties of Copolymers with Tailored Sequence Distribution by Controlled/Living Radical Polymerization268
20Controlled Synthesis of Amphiphilic Poly(methacrylate)-g-[poly(ester)/poly(ether)] Graft Terpolymers283
21New Materials Using Atom Transfer Radical Polymerization: Microcapsules Containing Polar Core Oil299
22Synthesis of Poly(N,N-Dimethylacrylamide) Brushes from Functionalized Latex Surfaces by Aqueous Atom Transfer Radical Polymerization316
23End-Functional Polystyrenes via Quasiliving Atom Transfer Radical Polymerization and New Polymer Structures Therefrom331
24A Strategy to Prepare Anemone-Shaped Polymer Brush by Controlled/Living Radical Polymerization342
25Surface Modification of Ethylene-Vinyl Alcohol Copolymer Films by Surface-Confined Atom Transfer Radical Polymerization352
26Polymers, Particles, and Surfaces with Hairy Coatings: Synthesis, Structure, Dynamics, and Resulting Properties366
27Photoinduced Free Radical Promoted Cationic Block Copolymerization by Using Macrophotoinitiators Prepared by ATRP and Ring-Opening Polymerization Methods383
28Bioinspired Triblock Copolymers Prepared by Atom Transfer Radical Copolymerization394
29Influence of Solvent and Polymer Chain Length on the Homolysis of SG1-Based Alkoxyamines
30Impact of Dilution on the Rate Constant of Termination in Nitroxide-Mediated Polymerization424
31Nitroxide-Mediated Polymerization in Miniemulsion: A Direct Way from Bulk to Aqueous Dispersed Systems438
32The Use of PROXYL Nitroxides in Nitroxide-Mediated Polymerization452
33Nitroxide-Mediated Semibatch Polymerization for the Production of Low-Molecular Weight Solvent-Borne Coatings Resins466
34Boroxyl-Based Radical Initiators and Polymerization481
35Controlled Radical Polymerization of Alkyl Methacrylates in the Presence of NO/NO[subscript 2] Mixtures496
36Kinetics and Mechanism of RAFT Polymerization520
37On the Importance of Xanthate Substituents in the MADIX Process536
38Influences of the Structural Design of RAFT Agents on Living Radical Polymerization Kinetics551
39Vinylidene Chloride Copolymerization with Methyl Acrylate by Degenerative Chain Transfer570
40RAFT Polymerization in Homogeneous Aqueous Media586
41RAFT Polymers: Novel Precursors for Polymer-Protein Conjugates603
42New Concepts for Controlled Radical Polymerization: The DPE System619
43Organotellurium-Mediated Living Radical Polymerization631
Author Index645
Subject Index647


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Advances in Controlled/Living Radical Polymerization, 
Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis, Advances in Controlled/Living Radical Polymerization

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Advances in Controlled/Living Radical Polymerization, 
Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis, Advances in Controlled/Living Radical Polymerization

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Advances in Controlled/Living Radical Polymerization, 
Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis, Advances in Controlled/Living Radical Polymerization

Advances in Controlled/Living Radical Polymerization

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