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Activation and Functionalization of C-H Bonds Book

Activation and Functionalization of C-H Bonds
Activation and Functionalization of C-H Bonds, 
<em>Activation and Functionalization of C-H Bonds</em> explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa, Activation and Functionalization of C-H Bonds has a rating of 3 stars
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Activation and Functionalization of C-H Bonds, Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa, Activation and Functionalization of C-H Bonds
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  • Activation and Functionalization of C-H Bonds
  • Written by author Karen I. Goldberg
  • Published by An American Chemical Society Publication, July 2004
  • Activation and Functionalization of C-H Bonds explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa
  • Carbon and hydrogen hook up a lot, more than any other two molecules in all of organic chemistry. But they have their own ideas about when, where, and why to do it, and have proved notoriously recalcitrant when chemists try what they call selective chemic
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1Organometallic C-H bond activation : an introduction1
2C-H bond activation by iridium and rhodium complexes : catalytic hydrogen-deuterium exchange and C-C bond-forming reactions
3Alkane complexes as intermediates in C-H bond activation reactions56
4C-C versus C-H bond oxidative addition in PCX (X=P,N,O) ligand systems : facility, mechanism, and control70
5Kinetic and equilibrium deuterium isotope effects for C-H bond reductive elimination and oxidative addition reactions involving the Ansa-tungstenocene methyl-hydride complex [Me[subscript 2]Si(C[subscript 5]Me[subscript 4])[subscript 2]]W(Me)H86
6Alkane C-H bond activation by O-donor Ir complexes105
7Lanthanide complexes : electronic structure and H-H, C-H, and Si-H bond activation from a DFT perspective116
8Catalytic, thermal, regioselective functionalization of alkanes and arenes with borane reagents136
9C-H bond functionalization in complex organic synthesis155
10Pincer and chelate N-heterocyclic carbene complexes of Rh, Ir, and Pd : synthetic routes, dynamics, catalysis, abnormal binding, and counterion effects169
11Sequential hydrocarbon C-H bond activations by 16-electron organometallic complexes of molybdenum and tungsten184
12Alkane transfer-dehydrogenation catalyzed by a pincer-ligated iridium complex198
13DFT calculations on the mechanisms of (PCB)Ir-catalyzed acceptorless dehydrogenation of alkanes : realistic computational models and free energy considerations216
14Double cyclometalation : implications for C-H oxidative addition with PCB pincer compounds of iridium234
15C-H bond activation at Pt(II) : a route to selective alkane oxidation?250
16Competitive trapping of equilibrating Pt(IV) hydridoalkyl and Pt(II) alkane complexes : a valuable tool for the mechanistic investigation of C-H activation reactions264
17Mechanisms of reactions related to selective alkane oxidation by Pt complexes283
18Hydrocarbon C-H bond activation with Tp'Pt complexes303
19C-H bond activation with neutral platinum methyl complexes
20Issues relevant to C-H activation at platinum(II) : comparative studies between cationic, zwitterionic, and neutral platinum(II) compounds in benzene solution334
21Non-organometallic mechanisms for C-H bond oxidation : hydrogen atom versus electron versus hydride transfer356
22Oxidation of organic molecules with molecular oxygen catalyzed by heterometallic complexes370
23Catalytic hydrocarbon oxidations involving coreductants379
24New applications of electrophilic aromatic C-H activation with metal trifluoroacetates393
25Reengineering of organic-based metal active sites for oxidations and oxygenations407


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Activation and Functionalization of C-H Bonds, 
<em>Activation and Functionalization of C-H Bonds</em> explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa, Activation and Functionalization of C-H Bonds

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Activation and Functionalization of C-H Bonds, 
<em>Activation and Functionalization of C-H Bonds</em> explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa, Activation and Functionalization of C-H Bonds

Activation and Functionalization of C-H Bonds

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Activation and Functionalization of C-H Bonds, 
<em>Activation and Functionalization of C-H Bonds</em> explores recent developments in the reaction chemistry of solution-phase transition-metal based systems with simple hydrocarbons and with more complex organic molecules. More than 20 internationa, Activation and Functionalization of C-H Bonds

Activation and Functionalization of C-H Bonds

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