Controlled - Living Radical Polymerization: Progress in ATRP, NMP and RAFT Book

	Preface	xi
	Advances in Conventional and Controlled Radical Polymerization
1.	Comparison and Classification of Controlled/Living Radical Polymerizations	2
2.	Kinetics of Living Radical Polymerization	27
3.	Initiation and Termination Rates Associated with Free-Radical Polymerization in Extended Ranges of Temperature and Pressure	39
4.	Stereochemistry in Radical Polymerization of Vinyl Esters	57
5.	Electron Paramagnetic Resonance Study of Conventional and Controlled Radical Polymerizations	68
6.	Models for Free-Radical Copolymerization Propagation Kinetics	82
7.	Topochemical Polymerization of Diene Monomers in the Crystalline State to Control the Stereochemistry of the Polymers	93
	Nitroxide-Mediated Polymerization
8.	Use of Phosphonylated Nitroxides and Alkoxyamines in Controlled/"Living" Radical Polymerization	108
9.	Progress Toward a Universal Initiator for Nitroxide Mediated 'Living' Free Radical Procedures	123
10.	Nitroxide-Mediated Controlled Free-Radical Emulsion and Miniemulsion Polymerizations of Styrene	138
11.	Triazolinyl Radicals: Toward a New Mechanism in Controlled Radical Polymerization	152
	Atom Transfer Radical Polymerization
12.	Living Radical Polymerization of Styrene: RuCl[subscript 2](PPh[subscript 3])[subscript 3] and Alkyl Iodide-Based Initiating Systems	168
13.	Copper-Mediated Living Radical Polymerization Utilizing Biological and End Group Modified Poly(ethylene-co-butylene) Macroinitiators	182
14.	Atom Transfer Radical Copolymerization of Styrene and Butyl Acrylate	197
15.	The Copper Catalyst in Atom Transfer Radical Polymerizations: Structural Observations	211
16.	Atom Transfer Radical Polymerization Mediated by Ruthenium(II)-Arene Complexes	223
17.	Polychloroalkanes as ATRP Initiators: Fundamentals and Application to the Synthesis of Block Copolymers from the Combination of Conventional Radical Polymerization and ATRP	234
18.	Controlled Radical Polymerization Utilizing Preformed Metal Complexes Based on Substituted Bipyridines and Terpyridines	248
19.	Reverse Atom Transfer Radical Polymerization Using AIBN or BPO as Initiator	263
20.	Synthesis of Defined Polymers by Reversible Addition-Fragmentation Chain Transfer: The RAFT Process	278
21.	Preparation of Macromonomers via Chain Transfer with and without Added Chain Transfer Agent	297
22.	End-Group Control in Catalytic Chain Transfer Polymerization	313
	New Materials by Controlled Radical Polymerization
23.	Synthesis of Polystyrene-Polyacrylate Block Copolymers by Nitroxide-Mediated Radical Polymerization	334
24.	Functionalized Polymers by Atom Transfer Radical Polymerization	347
25.	Copolymerization of n-Butyl Acrylate with Methyl Methacrylate and PMMA Macromonomers by Conventional and Atom Transfer Radical Copolymerization	361
26.	Quantitative Derivatizations of 1-Chloro-1-phenylethyl Chain End of Polystyrene Obtained by Quasiliving Atom Transfer Radical Polymerization	372
27.	Synthesis of Alternating Copolymers of N-Substituted Maleimides with Styrene via Atom Transfer Radical Polymerization	384
28.	Controlled Radical Copolymerization of Styrene and Acrylonitrile	394
29.	Synthesis of Oligomers by Stable Free Radical Polymerization of Acrylates, Methacrylates, and Styrene with Alkoxyamine Initiators	408
30.	Potential Impact of Controlled Radical Polymerization on Markets for Polymeric Materials	427
	Indexes
	Author Index	443
	Subject Index	445