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Phase-Transfer Catalysis : Mechanisms and Syntheses Book

Phase-Transfer Catalysis : Mechanisms and Syntheses
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Phase-Transfer Catalysis : Mechanisms and Syntheses, Featuring contributions from international experts, this volume presents the mechanism of phase-transfer catalysis and provides practical research guidelines and suggestions for developing new applications. It discusses organic synthesis and polymer , Phase-Transfer Catalysis : Mechanisms and Syntheses
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  • Phase-Transfer Catalysis : Mechanisms and Syntheses
  • Written by author Marc E. Halpern
  • Published by American Chemical Society, 1997/05/01
  • Featuring contributions from international experts, this volume presents the mechanism of phase-transfer catalysis and provides practical research guidelines and suggestions for developing new applications. It discusses organic synthesis and polymer
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Preface
1 Recent Trends in Industrial and Academic Phase-Transfer Catalysis 1
2 Modern Perspectives on the Mechanisms of Phase-Transfer Catalysis 10
3 Mechanisms and Applications of Solid-Liquid Phase-Transfer Catalysis 29
4 New Results in the Mechanism and Application of Phase-Transfer Catalysis 41
5 Adsorption on Interfaces and Solvation in Phase-Transfer Catalysis 52
6 Phase-Transfer and Micellar Catalysis in Two-Phase Systems 68
7 A New Interfacial Mechanism for Asymmetric Alkylation by Phase-Transfer Catalysis 89
8 Integrated Guideline for Choosing a Quaternary Ammonium Salt as a Phase-Transfer Catalyst To Enhance Reactivity and Separation 97
9 How To Influence Reaction Paths by Phase-Transfer Catalyst Structure 108
10 Amino Acid and Peptide Synthesis Using Phase-Transfer Catalysis 124
11 Use of Chiral Quaternary Salts in Asymmetric Synthesis 136
12 Fluoride Anion as a Base and a Nucleophile in Phase-Transfer Catalysis in Uncharged Species 148
13 Anomeric Group Transformations Under Phase-Transfer Catalysis 163
14 Michael Addition of 2-Phenylcyclohexanone to Chalcone Under Phase-Transfer Catalysis Conditions 181
15 Synthesis of Sulfides, Thiol Esters, and Cyclic Polythiaethers from Thioiminium Salts with a Phase-Transfer Catalyst 190
16 Microwave-Irradiated Alkylations of Active Methylenes Under Solid-Liquid Phase-Transfer Catalytic Conditions 203
17 Chemical Modification of Polymers via a Phase-Transfer Catalyst or Organic Strong Base 214
18 Synthesis of Aromatic Polyesters Bearing Pendant Reactive Groups by Phase-Transfer Catalysis 231
19 Polystyrene-Supported Onium Salts as Phase-Transfer Catalysts: Their State and Reactivity in Phase-Transfer Reaction Conditions 248
20 Rate-Limiting Step in Triphase Catalysis for the Esterification of Phenols 261
21 Multisite Phase-Transfer Catalyst for Organic Transformations 277
22 Cation-Binding Properties of Sodium-Selective 16-Crown-5 Derivatives 293
Author Index 303
Affiliation Index 303
Subject Index 304


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Phase-Transfer Catalysis : Mechanisms and Syntheses, 
Featuring contributions from international experts, this volume presents the mechanism of phase-transfer catalysis and provides practical research guidelines and suggestions for developing new applications. It discusses organic synthesis and polymer , Phase-Transfer Catalysis : Mechanisms and Syntheses

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Phase-Transfer Catalysis : Mechanisms and Syntheses, 
Featuring contributions from international experts, this volume presents the mechanism of phase-transfer catalysis and provides practical research guidelines and suggestions for developing new applications. It discusses organic synthesis and polymer , Phase-Transfer Catalysis : Mechanisms and Syntheses

Phase-Transfer Catalysis : Mechanisms and Syntheses

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Phase-Transfer Catalysis : Mechanisms and Syntheses, 
Featuring contributions from international experts, this volume presents the mechanism of phase-transfer catalysis and provides practical research guidelines and suggestions for developing new applications. It discusses organic synthesis and polymer , Phase-Transfer Catalysis : Mechanisms and Syntheses

Phase-Transfer Catalysis : Mechanisms and Syntheses

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