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Introduction | ||
Abbreviations | ||
1 | Selectivity in organic synthesis: stereochemical vocabulary | 1 |
2 | Classification of stereochemical reactions used in this book | 37 |
3 | Type 0 reactions: reactions in which no new chiral centres are created | 49 |
4 | Type I reactions: those proceeding with either inversion or with retention of configuration at a single chiral centre | 79 |
5 | Simple chirality transfer reactions: those in which a single chiral centre is transferred with concomitant migration of one or more double bonds | 109 |
6 | Type II reactions: simple diastereoselectivity in 1,2-additions to alkenes, Diels-Alder and 1,3-dipolar cycloadditions and the ene reaction | 147 |
7 | Type II reactions: occasional diastereoselectivity | 191 |
8 | Type II reactions: simple diastereoselectivity in the aldol and related reactions | 217 |
9 | Type III reactions: those involving asymmetric induction | 243 |
10 | Substrate-controlled diastereoselective reactions (Type III[subscript s.c.]) mediated by stereoelectronic effects: torsional strain and [sigma]-[pi] interactions | 273 |
11 | Substrate-controlled diastereoselective reactions (Type III[subscript s.c.]) mediated by ring formation | 315 |
12 | Type III reagent-controlled reactions (Type III[subscript r.c.]) | 359 |
13 | Type II/III reactions and those involving chirality transfer | 381 |
14 | Catalytic enantioselective reactions (Type III[subscript cat. enant.]) | 419 |
15 | Type III[subscript s.c./r.c.] reactions (Double asymmetric induction) | 473 |
16 | Type III reactions of diastereotopic and enantiotopic atoms and groups; enzyme catalysed reactions | 489 |
Index | 523 |
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Add Stereoselective Synthesis, Introduces a new, simplified classification for stereoselective reactions based on changes in the number of chiral centres taking place, emphasizing the three-dimensional representations of transition states in which stereoselectivity is determined. Using, Stereoselective Synthesis to your collection on WonderClub |