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Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, USA, October 2001 Book

Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, USA, October 2001
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Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, USA, October 2001, , Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, USA, October 2001
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  • Catalyst Deactivation 2001: Proceedings of the 9th International Symposium, Lexington, KY, USA, October 2001
  • Written by author J.J. Spivey
  • Published by Elsevier Science, September 2001
  • This proceedings contains the papers presented at the 9th International Symposium on Catalyst Deactivation, held in Lexington, KY, USA, on 7-10 October 2001.
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Preface
Whisker Carbon Revisited1
Various Forms of the Carbonaceous Deposit on the Model Cobalt Catalyst Studied in Hydrogenation of Ethylene13
Hydrodechlorination of 1,2-Dichloropropane over Pt-Cu/C Catalysts: Coke Formation Determined by a Novel Technique - TEOM21
Influence of the Aging of Zeolite Coke on Composition and Deactivating Effect29
Gas Phase Selective Hydrogenation of Acetylene. Importance of the Formation of Ni-Co and Ni-Cu Bimetallic Clusters on the Selectivity and Coke Deposition37
Coke Formation on H-mordenite Catalyst during the Benzene Transalkylation with C[subscript 9+] Aromatics45
Characterization of Structure and Combustion Behavior of the Coke formed on a Hydroisomerization Catalyst53
The Effects of Pore Structure on Catalyst Deactivation by Coke Formation61
Mechanistic Studies of Formation of Carbon Deposits on Supported Pt Catalysts during Wet Oxidation of Phenol69
Coke Deactivation of Acid Sites on ZSM-5 Zeolite77
CO[subscript 2] Reforming of Methane. Effect of Ni-SiO[subscript 2] Interactions on Carbon Deposition85
A Model for Reforming on Ni Catalyst with Carbon Formation and Deactivation93
Studies on Carbon Deposition of the Nickel-Based Catalysts Used for Carbon Dioxide Reforming of Methane101
The Nature of Coke on Platinum over Tungsten Oxide Promoted Zirconia during n-Hexane Isomerization109
Deactivation of a Zirconia Supported Chromia Aromatization Catalyst Investigated by in-situ H-D Tracer Experiments117
Study of Deactivation of Iron-Based Fischer-Tropsch Synthesis Catalysts125
Deactivation and Regeneration of Alkali Metal Promoted Iron Fischer-Tropsch Synthesis Catalysts133
Stability of K-La[subscript 2]O[subscript 3] Catalysts during the Combustion of Diesel Soot. High Frequency CO[subscript 2] Pulses and Soot-Catalyst Contacting Studies141
Study of the Sintering of a DeNO[subscript x] Commercial Catalyst149
The Effect of Catalyst Loading on the Sintering of Supported Pd/Al[subscript 2]O[subscript 3] Automotive Catalysts157
Is it Absolutely Safe To Discard Spent Catalysts after Preoxidation?165
Deactivation of Chromium Oxide Catalyst for the Removal of Perchloroethylene (PCE)173
Isobutane Alkylation with C[subscript 4] Olefins: Regeneration of Metal-containing Catalysts181
Deactivation of Pd-Based Combustion Catalysts Supported on Modified Alumina189
Prediction of the Performance of Coked and Regenerated FCC Catalyst Mixtures197
A Deactivation Model for Methanol-Stream Reformation on Cu/ZnO/Al[subscript 2]O[subscript 3] Catalyst for Optimizing the Production of Fuel-Cell Hydrogen205
Selective Acid-Base Poisoning on Bifunctional Alkylation Reaction213
Enhanced Isooctane Yields for 1-Butene/Isobutane Alkylation on SiO[subscript 2]-Supported Nafion in Supercritical Carbon Dioxide221
Deactivation of CuO/ZnO and Cuo/ZrO[subscript 2] Catalysts for Oxidative Methanol Reforming229
Deactivation of Sulfated Zirconia during the Isomerization of n-Butane: Experiments and Kinetic Model237
An Auger Electron Spectroscopy Study of SO[subscript 2] Adsorption on Cerium-Zirconia Mixed Metal Oxides247
Catalyst Deactivation during Catalytic Cracking of N-Octane, Iso-octane and 1-Octane over USHY Zeolite at Mild Conditions and Short Times on Stream255
Regeneration of Ni and Ni-Cr/Al[subscript 2]O[subscript 3] Catalysts for Methane Reforming Reactions263
Processes Occurring during Deactivation/Regeneration of a Vanadia/Alumina Catalyst under Propane Dehydrogenation Conditions271
Study of Industrial and Laboratory Regeneration of Pt-Re/Al[subscript 2]O[subscript 3] Catalysts279
Enhanced Performance of K-Doped PtSn/[gamma]-Al[subscript 2]O[subscript 3] Catalysts for Isobutane Dehydrogenation287
The Complex Role of Bismuth as Promoting Element To Inhibit Deactivation of Pd-Bi/C Catalyses in the Selective Oxidation of Glucose to Gluconic acid295
Deactivation of Mg[subscript y]AlO[subscript x] Mixed Oxides during Aldol Condensation Reactions of Ketones303
Regeneration of Supported Palladium Catalyst for Selective Hydrogenation of Acetylene311
Contribution to the Design of an Adiabetic Fixed Bed Reactor for the MTG Process Under Reaction-Regeneration Cycles319
Quinone Mediated Stabilization of a Palladium Catalyst for the Synthesis of Hydrogen Peroxide from Carbon Monoxide, Water and Oxygen327
Recent Developments in the Catalyst Regeneration for the Beckmann Rearrangement of Cyclohexanone Oxime to [epsilon]-Caprolactam335
Cyclohexane as a Probe To Nickel Vanadium Interaction in FCC Catalysts343
Metals on a Novel USY Zeolite after Hydrothermal Aging351
Characterisation of Coke on Deactivated Hydrodesulfurisation Catalysts and a Novel Approach to Catalyst Regeneration359
Origin of Deactivation of 5A Adsorbents during the Separation of N- and iso-alkanes367
Regeneration of Au/[gamma]-Al[subscript 2]O[subscript 3] Deactivated by CO Oxidation375
Partial Oxidation of Toluene to Benzaldehyde over Vanadium Antimonate Catalysts Doped with Titanium. The Influence of the Antimony Content on the Deactivation Process383
Hydrogen Production by Catalytic Cracking of Methane Using Ni-Al[subscript 2]O[subscript 3] Catalysts, Influence of the Operating Conditions391
Deactivation and Regeneration/Redispersion Chemistry of Pt/KL-Zeolite399
A Comparison of Fischer-Tropsch Synthesis in a Slurry Bubble Column Reactor and a Continuous Stirred Tank Reactor407
Deactivation of Ru Promoted Co/Al[subscript 2]O[subscript 3] Catalysts for Fischer-Tropsch Synthesis415
Hydrothermal Stability of Co/SiO[subscript 2] Fischer-Tropsch Synthesis Catalysts423
Effects of Additives on the Hydrodesulfurization of Dibenzothiophene on Nitrided Molybdena-Alumina Catalysts431
Mathematical Model for the Deactivation of Pt/Alumina Catalyst during the Hydrodechlorination of 1,1,1-Trichloroethane439
Modeling of the Regeneration of a Coked Fixed Bed Catalyst Based on Kinetic Studies of Coke Burn-off447
Kinetic Modeling for Deactivation by Coke Deposition of a HZSM-5 Zeolite Catalyst in the Transformation of Aqueous Ethanol into Hydrocarbons455
Sulfur Poisoning in Catalytic Combustion of Industrial Waste463
EXAFS and Activity Studies of the Poisoning Effect of Al on Pt/Al[subscript 2]O[subscript 3] Catalysts during Oxidation Reactions471
Catalysts Surface Poisoning by Arsenic; Mechanism of Triphenylarsine Interaction with Alumina Supported Nickel479
Deactivation of Bulk Iron Oxide Catalysts during Methane Combustion487
Sintering of Metal Crystallites in Ni/Al[subscript 2]O[subscript 3] Catalysts Used for Steam Reforming: an Experimental Design Study495
Realistic Particle Size Distributions during Sintering by Ostwald Ripening503
Author Index511


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