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Preface | ||
1 | Polymers in Solution | 1 |
1.1 | Flexible homopolymers | 1 |
1.2 | Copolymers | 15 |
1.3 | Polyelectrolytes | 18 |
2 | General Features of Polymers at Interfaces | 27 |
2.1 | Description of the interfacial region | 27 |
2.2 | Adsorbed amount | 28 |
2.3 | Structural aspects | 31 |
2.5 | Competitive adsorption | 35 |
2.6 | Adsorption kinetics | 36 |
2.7 | Effects of flow fields | 37 |
2.8 | Depletion | 37 |
2.9 | Fluid interfaces | 39 |
2.10 | Polymer melts | 39 |
3 | Experimental Methods | 43 |
3.1 | Experimental systems | 43 |
3.2 | Adsorption isotherms | 48 |
3.3 | Bound fraction and train density | 52 |
3.4 | Adsorbed layer thickness | 66 |
3.5 | Volume fraction profile | 80 |
3.6 | Kinetics | 92 |
4 | Theoretical Methods | 101 |
4.1 | Overview of polymer adsorption theory | 101 |
4.2 | Self-consistent-field lattice model for homopolymer adsorption | 154 |
4.3 | Extensions of the SCF-model | 180 |
4.4 | Analytical approximations for special cases | 208 |
5 | Homopolymer Adsorption | 234 |
5.2 | Structure of the adsorbed layer | 236 |
5.3 | Adsorbed amount | 265 |
5.4 | Preferential adsorption | 271 |
5.5 | Kinetic aspects | 286 |
6 | Adsorption of Copolymers | 301 |
6.1 | Block copolymers | 301 |
6.2 | Random copolymers | 321 |
7 | Electrostatic Effects: Charged surfaces and polyelectrolyte adsorption | 343 |
7.2 | Neutral polymers on charged surfaces | 344 |
7.3 | Polyelectroloyte adsorption | 346 |
7.4 | Structural features of adsorbed polyelectrolytes | 369 |
7.5 | Kinetic aspects | 371 |
8 | Terminally-Attached Chains | 376 |
8.2 | Mushrooms, pancakes, and brushes | 376 |
8.3 | Isolated chains | 378 |
8.4 | Volume fraction profiles | 380 |
8.5 | Layer thickness | 394 |
8.6 | Bound fraction | 397 |
9 | Fluid Interfaces | 400 |
9.2 | The liquid-liquid interface | 401 |
9.3 | The liquid-air interface | 411 |
9.4 | Polymer-polymer interfaces | 415 |
10 | Depletion | 419 |
10.2 | Depletion at hard surfaces | 420 |
10.3 | Depletion at 'soft' surfaces | 426 |
10.4 | Direct experimental studies of depletion | 429 |
11 | Interactions in the Presence of Polymers | 435 |
11.2 | Polymer adsorption effects | 440 |
11.3 | Polymer depletion effects | 454 |
Appendix I Solution properties of some selected polymers | 462 | |
Appendix II Nuclear properties of some selected elements | 465 | |
Appendix III Multiple pulse theory | 466 | |
Appendix IV Neutron scattering | 469 | |
Appendix V Lattice chains versus real chains | 472 | |
Glossary of symbols | 475 | |
Key word index | 495 |
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Add Polymers At Interfaces, This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h, Polymers At Interfaces to the inventory that you are selling on WonderClubX
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Add Polymers At Interfaces, This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h, Polymers At Interfaces to your collection on WonderClub |