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Polymers At Interfaces Book

Polymers At Interfaces
Polymers At Interfaces, This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h, Polymers At Interfaces has a rating of 3.5 stars
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Polymers At Interfaces, This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h, Polymers At Interfaces
3.5 out of 5 stars based on 2 reviews
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  • Polymers At Interfaces
  • Written by author G. J. Fleer
  • Published by Springer-Verlag New York, LLC, September 1993
  • This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h
  • This book is concerned with the configuration of polymers at the interfacial zone between two other phases or immiscible components. In recent years, developments in technology combined with increased attention from specialists in a wide range of fields h
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Preface
1Polymers in Solution1
1.1Flexible homopolymers1
1.2Copolymers15
1.3Polyelectrolytes18
2General Features of Polymers at Interfaces27
2.1Description of the interfacial region27
2.2Adsorbed amount28
2.3Structural aspects31
2.5Competitive adsorption35
2.6Adsorption kinetics36
2.7Effects of flow fields37
2.8Depletion37
2.9Fluid interfaces39
2.10Polymer melts39
3Experimental Methods43
3.1Experimental systems43
3.2Adsorption isotherms48
3.3Bound fraction and train density52
3.4Adsorbed layer thickness66
3.5Volume fraction profile80
3.6Kinetics92
4Theoretical Methods101
4.1Overview of polymer adsorption theory101
4.2Self-consistent-field lattice model for homopolymer adsorption154
4.3Extensions of the SCF-model180
4.4Analytical approximations for special cases208
5Homopolymer Adsorption234
5.2Structure of the adsorbed layer236
5.3Adsorbed amount265
5.4Preferential adsorption271
5.5Kinetic aspects286
6Adsorption of Copolymers301
6.1Block copolymers301
6.2Random copolymers321
7Electrostatic Effects: Charged surfaces and polyelectrolyte adsorption343
7.2Neutral polymers on charged surfaces344
7.3Polyelectroloyte adsorption346
7.4Structural features of adsorbed polyelectrolytes369
7.5Kinetic aspects371
8Terminally-Attached Chains376
8.2Mushrooms, pancakes, and brushes376
8.3Isolated chains378
8.4Volume fraction profiles380
8.5Layer thickness394
8.6Bound fraction397
9Fluid Interfaces400
9.2The liquid-liquid interface401
9.3The liquid-air interface411
9.4Polymer-polymer interfaces415
10Depletion419
10.2Depletion at hard surfaces420
10.3Depletion at 'soft' surfaces426
10.4Direct experimental studies of depletion429
11Interactions in the Presence of Polymers435
11.2Polymer adsorption effects440
11.3Polymer depletion effects454
Appendix I Solution properties of some selected polymers462
Appendix II Nuclear properties of some selected elements465
Appendix III Multiple pulse theory466
Appendix IV Neutron scattering469
Appendix V Lattice chains versus real chains472
Glossary of symbols475
Key word index495


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