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Preface | ||
Ch. 1 | Electrode Potentials | 1 |
1.2 | Electrochemical Cell Thermodynamics | 5 |
1.3 | Some Uses of Standard Potentials | 13 |
1.4 | Measurement of Cell Potentials | 27 |
1.5 | Reference and Indicator Electrodes | 31 |
1.6 | Ion-Selective Electrodes | 35 |
1.7 | Chemical Analysis by Potentiometry | 39 |
1.8 | Batteries and Fuel Cells | 44 |
Ch. 2 | The Electrified Interface | 59 |
2.1 | The Electric Double Layer | 59 |
2.2 | Some Properties of Colloids | 68 |
2.3 | Electrokinetic Phenomena | 73 |
2.4 | Electrophoresis and Related Phenomena | 81 |
2.5 | Electrode Double-Layer Effects | 85 |
2.6 | Debye-Huckel Theory | 90 |
Ch. 3 | Electrolytic Conductance | 109 |
3.1 | Conductivity | 109 |
3.2 | Conductance Applications | 125 |
3.3 | Diffusion | 128 |
3.4 | Membrane and Liquid Junction Potentials | 136 |
Ch. 4 | Voltammetry of Reversible Systems | 151 |
4.1 | Diffusion-Limited Current | 152 |
4.2 | Experimental Techniques | 165 |
4.3 | A Survey of Electroanalytical Methods | 174 |
4.4 | Cyclic Voltammetry | 183 |
4.5 | Polarography | 194 |
4.6 | Polarographic Variations | 201 |
4.7 | The Rotating-Disk Electrode | 207 |
4.8 | Microelectrodes | 215 |
4.9 | Applications | 223 |
Ch. 5 | Mechanisms of Electrode Processes | 247 |
5.2 | Spectroelectrochemistry | 257 |
5.3 | Steady-State Voltammetry and Polarography | 269 |
5.4 | Chronoamperometry and Chronopotentiometry | 287 |
5.5 | Cyclic Voltammetry | 296 |
Ch. 6 | Electron-Transfer Kinetics | 315 |
6.1 | Kinetics of Electron Transfer | 315 |
6.2 | Current-Overpotential Curves | 325 |
6.3 | Electron-Transfer Rates from Voltammetry | 338 |
6.4 | Faradaic Impedance | 351 |
Ch. 7 | Electrolysis | 371 |
7.1 | Bulk Electrolysis | 371 |
7.2 | Analytical Applications of Electrolysis | 376 |
7.3 | Electrosynthesis | 390 |
7.4 | Industrial Electrolysis Processes | 396 |
7.5 | Corrosion | 412 |
App.1 Bibliography | 427 | |
App.2 Symbols and Units | 433 | |
App.3 Electrochemical Data | 438 | |
App.4 Laplace Transform Methods | 448 | |
App.5 Digital Simulation Methods | 462 | |
App.6 Answers to Selected Problems | 467 | |
Author Index | 472 | |
Subject Index | 477 |
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