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Statistical Mechanics: Entropy, Order Parameters and Complexity Book

Statistical Mechanics: Entropy, Order Parameters and Complexity
Statistical Mechanics: Entropy, Order Parameters and Complexity, , Statistical Mechanics: Entropy, Order Parameters and Complexity has a rating of 3.5 stars
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Statistical Mechanics: Entropy, Order Parameters and Complexity, , Statistical Mechanics: Entropy, Order Parameters and Complexity
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  • Statistical Mechanics: Entropy, Order Parameters and Complexity
  • Written by author James P. Sethna
  • Published by Oxford University Press, USA, April 2006
  • In each generation, scientists must redefine their fields: abstracting, simplifying and distilling the previous standard topics to make room for new advances and methods. Sethna's book takes this step for statistical mechanics—a field rooted in p
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List of figuresxv
1What is statistical mechanics?1
Exercises4
1.1Quantum dice4
1.2Probability distributions5
1.3Waiting times6
1.4Stirling's approximation7
1.5Stirling and asymptotic series7
1.6Random matrix theory8
1.7Six degrees of separation9
1.8Satisfactory map colorings12
2Random walks and emergent properties15
2.1Random walk examples: universality and scale invariance15
2.2The diffusion equation19
2.3Currents and external forces20
2.4Solving the diffusion equation22
2.4.1Fourier23
2.4.2Green23
Exercises25
2.1Random walks in grade space25
2.2Photon diffusion in the Sun26
2.3Molecular motors and random walks26
2.4Perfume walk27
2.5Generating random walks28
2.6Fourier and Green28
2.7Periodic diffusion29
2.8Thermal diffusion30
2.9Frying pan30
2.10Polymers and random walks30
2.11Stocks, volatility, and diversification31
2.12Computational finance: pricing derivatives32
2.13Building a percolation network33
3Temperature and equilibrium37
3.1The microcanonical ensemble37
3.2The microcanonical ideal gas39
3.2.1Configuration space39
3.2.2Momentum space41
3.3What is temperature?44
3.4Pressure and chemical potential47
3.4.1Advanced topic: pressure in mechanics and statistical mechanics48
3.5Entropy, the ideal gas, and phase-space refinements51
Exercises53
3.1Temperature and energy54
3.2Large and very large numbers54
3.3Escape velocity54
3.4Pressure computation54
3.5Hard sphere gas55
3.6Connecting two macroscopic systems55
3.7Gas mixture56
3.8Microcanonical energy fluctuations56
3.9Gauss and Poisson57
3.10Triple product relation58
3.11Maxwell relations58
3.12Solving differential equations: the pendulum58
4Phase-space dynamics and ergodicity63
4.1Liouville's theorem63
4.2Ergodicity65
Exercises69
4.1Equilibration69
4.2Liouville vs. the damped pendulum70
4.3Invariant measures70
4.4Jupiter! and the KAM theorem72
5Entropy77
5.1Entropy as irreversibility: engines and the heat death of the Universe77
5.2Entropy as disorder81
5.2.1Entropy of mixing: Maxwell's demon and osmotic pressure82
5.2.2Residual entropy of glasses: the roads not taken83
5.3Entropy as ignorance: information and memory85
5.3.1Non-equilibrium entropy86
5.3.2Information entropy87
Exercises90
5.1Life and the heat death of the Universe91
5.2Burning information and Maxwellian demons91
5.3Reversible computation93
5.4Black hole thermodynamics93
5.5Pressure-volume diagram94
5.6Carnot refrigerator95
5.7Does entropy increase?95
5.8The Arnol'd cat map95
5.9Chaos, Lyapunov, and entropy increase96
5.10Entropy increases: diffusion97
5.11Entropy of glasses97
5.12Rubber band98
5.13How many shuffles?99
5.14Information entropy100
5.15Shannon entropy100
5.16Fractal dimensions101
5.17Deriving entropy102
6Free energies105
6.1The canonical ensemble106
6.2Uncoupled systems and canonical ensembles109
6.3Grand canonical ensemble112
6.4What is thermodynamics?113
6.5Mechanics: friction and fluctuations117
6.6Chemical equilibrium and reaction rates118
6.7Free energy density for the ideal gas121
Exercises123
6.1Exponential atmosphere124
6.2Two-state system125
6.3Negative temperature125
6.4Molecular motors and free energies126
6.5Laplace127
6.6Lagrange128
6.7Legendre128
6.8Euler128
6.9Gibbs-Duhem129
6.10Clausius-Clapeyron129
6.11Barrier crossing129
6.12Michaelis-Menten and Hill131
6.13Pollen and hard squares132
6.14Statistical mechanics and statistics133
7Quantum statistical mechanics135
7.1Mixed states and density matrices135
7.1.1Advanced topic: density matrices136
7.2Quantum harmonic oscillator139
7.3Bose and Fermi statistics140
7.4Non-interacting bosons and fermions141
7.5Maxwell-Boltzmann 'quantum' statistics144
7.6Black-body radiation and Bose condensation146
7.6.1Free particles in a box146
7.6.2Black-body radiation147
7.6.3Bose condensation148
7.7Metals and the Fermi gas150
Exercises151
7.1Ensembles and quantum statistics151
7.2Phonons and photons are bosons152
7.3Phase-space units and the zero of entropy153
7.4Does entropy increase in quantum systems?153
7.5Photon density matrices154
7.6Spin density matrix154
7.7Light emission and absorption154
7.8Einstein's A and B155
7.9Bosons are gregarious: superfluids and lasers156
7.10Crystal defects157
7.11Phonons on a string157
7.12Semiconductors157
7.13Bose condensation in a band158
7.14Bose condensation: the experiment158
7.15The photon-dominated Universe159
7.16White dwarfs, neutron stars, and black holes161
8Calculation and computation163
8.1The Ising model163
8.1.1Magnetism164
8.1.2Binary alloys165
8.1.3Liquids, gases, and the critical point166
8.1.4How to solve the Ising model166
8.2Markov chains167
8.3What is a phase? Perturbation theory171
Exercises174
8.1The Ising model174
8.2Ising fluctuations and susceptibilities174
8.3Waiting for Godot, and Markov175
8.4Red and green bacteria175
8.5Detailed balance176
8.6Metropolis176
8.7Implementing Ising176
8.8Wolff177
8.9Implementing Wolff177
8.10Stochastic cells178
8.11The repressilator179
8.12Entropy increases! Markov chains182
8.13Hysteresis and avalanches182
8.14Hysteresis algorithms185
8.15NP-completeness and kSAT186
9Order parameters, broken symmetry, and topology191
9.1Identify the broken symmetry192
9.2Define the order parameter192
9.3Examine the elementary excitations196
9.4Classify the topological defects198
Exercises203
9.1Topological defects in nematic liquid crystals203
9.2Topological defects in the XY model204
9.3Defect energetics and total divergence terms205
9.4Domain walls in magnets206
9.5Landau theory for the Ising model206
9.6Symmetries and wave equations209
9.7Superfluid order and vortices210
9.8Superfluids: density matrices and ODLRO211
10Correlations, response, and dissipation215
10.1Correlation functions: motivation215
10.2Experimental probes of correlations217
10.3Equal-time correlations in the ideal gas218
10.4Onsager's regression hypothesis and time correlations220
10.5Susceptibility and linear response222
10.6Dissipation and the imaginary part223
10.7Static susceptibility224
10.8The fluctuation-dissipation theorem227
10.9Causality and Kramers-Kronig229
Exercises231
10.1Microwave background radiation231
10.2Pair distributions and molecular dynamics233
10.3Damped oscillator235
10.4Spin236
10.5Telegraph noise in nanojunctions236
10.6Fluctuation-dissipation: Ising237
10.7Noise and Langevin equations238
10.8Magnetic dynamics238
10.9Quasiparticle poles and Goldstone's theorem239
11Abrupt phase transitions241
11.1Stable and metastable phases241
11.2Maxwell construction243
11.3Nucleation: critical droplet theory244
11.4Morphology of abrupt transitions246
11.4.1Coarsening246
11.4.2Martensites250
11.4.3Dendritic growth250
Exercises251
11.1Maxwell and van der Waals251
11.2The van der Waals critical point252
11.3Interfaces and van der Waals252
11.4Nucleation in the Ising model253
11.5Nucleation of dislocation pairs254
11.6Coarsening in the Ising model255
11.7Origami microstructure255
11.8Minimizing sequences and microstructure258
11.9Snowflakes and linear stability259
12Continuous phase transitions263
12.1Universality265
12.2Scale invariance272
12.3Examples of critical points277
12.3.1Equilibrium criticality: energy versus entropy278
12.3.2Quantum criticality: zero-point fluctuations versus energy278
12.3.3Dynamical systems and the onset of chaos279
12.3.4Glassy systems: random but frozen280
12.3.5Perspectives281
Exercises282
12.1Ising self-similarity282
12.2Scaling and corrections to scaling282
12.3Scaling and coarsening282
12.4Bifurcation theory283
12.5Mean-field theory284
12.6The onset of lasing284
12.7Renormalization-group trajectories285
12.8Superconductivity and the renormalization group286
12.9Period doubling288
12.10The renormalization group and the central limit theorem: short291
12.11The renormalization group and the central limit theorem: long291
12.12Percolation and universality293
12.13Hysteresis and avalanches: scaling296
AAppendix: Fourier methods299
A.1Fourier conventions299
A.2Derivatives, convolutions, and correlations302
A.3Fourier methods and function space303
A.4Fourier and translational symmetry305
Exercises307
A.1Sound wave307
A.2Fourier cosines307
A.3Double sinusoid307
A.4Fourier Gaussians
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