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Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications Book

Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications
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Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications, Vanadium is now known to be one of the more biologically important transition elements. This volume focuses on vanadium chemistry and biochemistry and summarizes the role of vanadium in treating diabetes, concluding with a discussion of a recent huma, Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications
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  • Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications
  • Written by author Alan S. Tracey, Debbie C. Crans
  • Published by American Chemical Society, 1999/01/01
  • Vanadium is now known to be one of the more biologically important transition elements. This volume focuses on vanadium chemistry and biochemistry and summarizes the role of vanadium in treating diabetes, concluding with a discussion of a recent huma
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Preface
1 The Chemistry of Vanadium in Aqueous and Nonaqueous Solution 2
2 Studies of Vanadate-Organic Ligand Systems Using Potentiometry and NMR Spectroscopy 30
3 Vanadium(V) Equilibria: Thermodynamic Quantities for Some Protonation and Condensation Reactions 51
4 Structural and Functional Models for Biogenic Vanadium Compounds 60
5 Synthesis, Structure and Reactivity of V[superscript v]-Thiolate and V[superscript v]-[eta][superscript 2]-Sulfenate Complexes 71
6 Peroxo, Hydroxylamido, and Acac Derived Vanadium Complexes: Chemistry, Biochemistry, and Insulin-Mimetic Action of Selected Vanadium Compounds 82
7 Interaction of the Vanadyl (VO[superscript 2+]) Cation with Guanosine Nucleotides and Elongation Factor Tu 104
8 Composition and Structure of Vanadium(V) Peroxo Complexes 117
9 Bis-Peroxo-Oxovanadium(V) Complexes of Histidine-Containing Peptides as Models for Vanadium Halo-Peroxidases 126
10 From the Speciation of Peroxovanadium Complexes in Aqueous Solution to the Chemistry of Haloperoxidases 136
11 Catalytic Oxidations with Biomimetic Vanadium Systems 146
12 Synthetic Models for Vanadium Haloperoxidases 157
13 Perspectives on Vanadium Biochemistry 170
14 Chloroperoxidase from Curvularia inaequalis: X-ray Structures of Native and Peroxide Form Reveal Vanadium Chemistry in Vanadium Haloperoxidases 186
15 Reactivity of Vanadium Bromoperoxidase 202
16 Vanadate-Containing Haloperoxidases and Acid Phosphatases: The Conserved Active Site 216
17 The Vanadium-Containing Nitrogenase System of Azotobacter vinelandii 228
18 A Possible Role for Amavadine in Some Amanita Fungi: A Unique Case in Biology 241
19 The Accumulation Mechanism of Vanadium by Ascidians: An Interdisciplinary Study between Biology and Chemistry on Extraordinary High Levels and Reduced Form of Vanadium in Vanadocytes 248
20 A New Class of Insulin-Mimetic Compounds. N,N-Dimethylhydroxamidovanadates: Aspects of Their Chemistry and Function 259
21 Vanadium Bioactivity on Cells in Culture 270
22 Pharmacology and Toxicology of Oxovanadium Species: Oxovanadium Pharmacology 278
23 The Nutritional Essentiality and Physiological Metabolism of Vanadium in Higher Animals 297
24 Insulin-like Effects of Vanadium; Reviewing In Vivo and In Vitro Studies and Mechanisms of Action 308
25 Mechanism of Insulin Mimetic Action of Peroxovanadium Compounds 316
26 Chemical and Pharmacological Studies of a New Class of Antidiabetic Vanadium Complexes 329
27 Structure-Activity Relationship of Insulin-Mimetic Vanadyl Complexes with VO(N[subscript 2]O[subscript 2]) Coordination Mode 344
28 Vanadium Salts in the Treatment of Human Diabetes Mellitus 353
Author Index 371
Subject Index 373


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Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications, 
Vanadium is now known to be one of the more biologically important transition elements. This volume focuses on vanadium chemistry and biochemistry and summarizes the role of vanadium in treating diabetes, concluding with a discussion of a recent huma, Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications

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Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications, 
Vanadium is now known to be one of the more biologically important transition elements. This volume focuses on vanadium chemistry and biochemistry and summarizes the role of vanadium in treating diabetes, concluding with a discussion of a recent huma, Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications

Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications

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Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications, 
Vanadium is now known to be one of the more biologically important transition elements. This volume focuses on vanadium chemistry and biochemistry and summarizes the role of vanadium in treating diabetes, concluding with a discussion of a recent huma, Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications

Vanadium Compounds : Chemistry, Biochemistry and Therapeutic Applications

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