Reactions in Solution: An Applied Analytical Approach Book

	Preface
1	Introduction	3
2	Quantitative Expression of the Effects of Complexation	14
	Review of the formation of metallic complexes in solution	14
	Complexation coefficients	17
	Raising the acidity by the effect of complexation	53
3	Solubilisation and Insolubilisation - Separation by Selective Dissolution or Precipitation	57
	Solubilisation of sparingly soluble molecules	58
	Solubility of metallic ions: insoluble hydroxides or oxides	64
	Precipitation or solubilisation of sparingly soluble metallic salts	76
	Phenomena accompanying the precipitation of solid compounds	88
4	Oxidations and Reductions	91
	Review of definitions and general properties of redox systems	91
	Conditional redox potentials	97
	Selective oxidations and reductions	118
5	Phase Transfer Reactions and Separations by Selective Extraction	142
	Principles of solvent extraction and of separations by extraction	142
	Extraction reactions by selective solvent action	147
	Phenomena that affect the rate of solvent extraction	184
	Extraction and separation by means of ion exchange resins	189
6	Molecular Solvents - Effects of the Solvent on the Reactivity of Solutes	227
	Solvation effects	230
	Solvolysis effects	250
	Correlation of acidobasic properties in different solvents	265
	Weakly dissociating solvents	283
7	Reactions in Molten Salts	301
	Oxoacidity	310
	Influence of oxoacidity on redox properties	338
	Special case of molten hydroxides	366
	Molten salts giving rise to systems of solvoacidity other than oxoacidity	398
App. A	Reactions Exploited in Hydrometallurgical Processes	441
App. B	Potentiometric Means for Experimental Control of Ion Activities in Solution	454
	Theoretical problems	475
	Index	545