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Polymer Interface and Adhesion Book

Polymer Interface and Adhesion
Polymer Interface and Adhesion, Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s, Polymer Interface and Adhesion has a rating of 3 stars
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Polymer Interface and Adhesion, Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s, Polymer Interface and Adhesion
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  • Polymer Interface and Adhesion
  • Written by author Wu
  • Published by Taylor & Francis, Inc., January 2001
  • Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s
  • Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s
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Preface
Acknowledgments
1.Interfacial Thermodynamics1
1.1Formulation of Interfacial Thermodynamics1
1.2Work of Adhesion and Work of Cohesion4
1.3Interfacial and Hydrostatic Equilibrium5
1.4Effect of Curvature on Vapor Pressure and Surface Tension7
1.5Spreading Pressure and Spreading Coefficient8
1.6Contact Angle Equilibrium: Young Equation11
1.7Contact Angle Hysteresis15
References26
2.Molecular Interpretations29
2.1Microscopic Theories of van der Waals Forces30
2.2Additivity and Fractional Contributions of Various types of Molecular Forces40
2.3Approximations for Unlike Molecules42
2.4Lennard-Jones Potential Energy Function44
2.5Attraction Between Macroscopic Bodies47
2.6Macroscopic Theory of van der Waals Forces: The Lifshitz Theory54
References62
3.Interfacial and Surface Tensions of Polymer Melts and Liquids67
3.1Surface Tensions of Polymer Melts and Liquids67
3.2Interfacial Tensions Between Polymers96
References129
4.Contact Angles of Liquids on Solid Polymers133
4.1Equilibrium Spreading Pressure133
4.2Spreading Coefficient139
4.3Effect of Temperature on Contact Angle139
4.4Effect of Primary and Secondary Transitions147
4.5Contact Angle and Heat of Wetting148
4.6Polarity of Liquids148
4.7Prediction of Contact Angles152
4.8Effect of Solute Adsorption on Contact Angle152
4.9Tabulation of Equilibrium Contact Angle157
4.10Distortion of Liquid Surfaces: Marangoni Effect161
4.11Spreading of Partially Submerged Drops164
References165
5.Surface Tension and Polarity of Solid Polymers169
5.1Determination of Surface Tension and Polarity169
5.2Surface Tension and Polarity of Organic Pigments198
5.3Constitutive Effect on Surface Tension201
5.4Morphological Effect on Surface Tension201
5.5Effects of Additives, Polymer Blends, Copolymers, Conformation, and Tacticity on Surface Tension209
References211
6.Wetting of High-Energy Surfaces215
6.1Introduction215
6.2Spreading on High-Energy Surfaces219
6.3Effect of Water and Organic Contaminations222
6.4Kinetics of Surface-Energy Variation229
References231
7.Dynamic Contact Angles and Wetting Kinetics235
7.1Introduction235
7.2Kinetics of Spontaneous Motion236
7.3Kinetics of Forced Motion247
References254
8.Experimental Methods for Contact Angles and Interfacial Tensions257
8.1Measurements of Contact Angles257
8.2Measurements of Interfacial and Surface Tensions of Polymer Liquids and Melts266
References274
9.Modifications of Polymer Surfaces: Mechanisms of Wettability and Bondability Improvements279
9.1Chemical Treatments280
9.2Flame and Thermal Treatments296
9.3Plasma Treatments298
9.4Photochemical Treatments322
9.5Crystalline Modifications of Polymer Surfaces323
9.6Miscellaneous Modifications327
References328
10.Adhesion: Basic Concept and Locus of Failure337
10.1Definitions337
10.2Basic Concept of Adhesive Bond Strength338
10.3Locus of Failure344
References354
11.Formation of Adhesive Bond359
11.1Elementary Processes in Adhesive Bond Formation359
11.2Wetting and Adhesion360
11.3Diffusion and Adhesion380
11.4Chemical Adhesion406
11.5Mechanical Adhesion434
References
12.Weak Boundary Layers449
12.1Weak-Boundary-Layer Theory449
12.2Examples of Weak Boundary Layers450
12.3Critique of Weak-Boundary-Layer Theory456
References460
13.Effect of Internal Stress on Bond Strength465
13.1Shrinkage of a Coating Adhering to a Substrate467
13.2Free Thickness Contraction in a Butt Joint470
13.3No Thickness Contraction in a Sandwich Structure472
13.4No Thickness Contraction in a Long, Narrow Adhesive Layer in an Annulus472
References473
14.Fracture of Adhesive Bond475
Part I.Fundamentals of Fracture Mechanics475
14.1Linear Elastic Fracture Mechanics476
14.2Local Plastic Flow484
14.3Generalization of Flaw Theory to Viscoelastic Materials: Rivlin and Thomas Theory486
14.4Properties of Fracture Energy488
Part II.Analysis and Testing of Adhesive Bonds497
14.5Tensile Tests (Butt Joints)497
14.6Shear Tests (Lap Joints)510
14.7Peel Tests (Peel Joints)530
14.8Cantilever Beam Tests555
14.9Other Fracture Energy Tests560
References563
15.Creep, Fatigue, and Environmental Effects571
Part I.Creep and Fatigue of Adhesive Joints571
15.1Creep Fracture572
15.2Fatigue Fracture579
Part II.Environmental Effects586
15.3Spontaneous Separation589
15.4Effect of Interfacial Chemical Bonds593
15.5Stress Corrosion Cracking and Fatigue in Wet Environment603
References609
Appendix ICalculation of Surface Tension and Its Nonpolar and Polar Components from Contact Angles by the Harmonic-Mean and the Geometric-Mean Methods613
Appendix IIUnit Conversion Tables619
Index621


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Polymer Interface and Adhesion, Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s, Polymer Interface and Adhesion

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Polymer Interface and Adhesion, Polymer Interface and Adhesion provides the critical basis for further advancement in this field. Combining the principles of interfacial science, rheology, stress analysis, and fracture mechanics, the book teaches a new approach to the analysis of long s, Polymer Interface and Adhesion

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