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Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis Book

Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis
Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis, The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions , Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis has a rating of 3 stars
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Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis, The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions , Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis
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  • Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis
  • Written by author S. Ted Oyama
  • Published by Elsevier BV, August 2008
  • The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions
  • The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions
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Sect. 1 Introduction 1

1 Rates, Kinetics, and Mechanisms of Epoxidation: Homogeneous, Heterogeneous, and Biological Routes S. Ted Oyama Oyama, S. Ted 3

Sect. 2 Homogeneous Catalysis 101

2 Unprecedented Selectivity in the H[subscript 2]O[subscript 2]Epoxidation of Simple Alkenes Imparted by Soft Pt(II) Lewis Acid Catalysts Giorgio Strukul Strukul, Giorgio Alessandro Scarso Scarso, Alessandro 103

3 Lewis Acid Catalyzed Epoxidation of Olefins Using Hydrogen Peroxide: Growing Prominence and Expanding Range Daryle H. Busch Busch, Daryle H. Guochuan Yin Yin, Guochuan Hyun-Jin Lee Lee, Hyun-Jin 119

4 Activation of Hydrogen Peroxide by Polyoxometalates Noritaka Mizuno Mizuno, Noritaka Kazuya Yamaguchi Yamaguchi, Kazuya Keigo Kamata Kamata, Keigo Yoshinao Nakagawa Nakagawa, Yoshinao 155

5 Oxaziridinium Salt-Mediated Catalytic Asymmetric Epoxidation Philip C. Bulman Page Page, Philip C. Bulman Benjamin R. Buckley Buckley, Benjamin R. 177

6 Selective Aerobic Radical Epoxidation of [alpha]-Olefins Catalyzed by N-Hydroxyphthalimide Carlo Punta Punta, Carlo Davide Moscatelli Moscatelli, Davide Ombretta Porta Porta, Ombretta Francesco Minisci Minisci, Francesco Cristian Gambarotti Gambarotti, Cristian Marco Lucarini Lucarini, Marco 217

Sect. 3 Heterogeneous Catalysis 231

7 Investigation of the Origins of Selectivity in Ethylene Epoxidation on Promoted and Unpromoted Ag/[alpha]-Al[subscript 2]O[subscript 3]Catalysts: A Detailed Kinetic, Mechanistic and Adsorptive Study Kenneth C. Waugh Waugh, Kenneth C. M. Hague Hague, M. 233

8 Computational Strategies for Identification of Bimetallic Ethylene Epoxidation Catalysts A. B. Mhadeshwar Mhadeshwar, A. B. M. A. Barteau Barteau,M. A. 265

9 Effect of Support on Ethylene Epoxidation on Ag, Au, and Au-Ag Catalysts Sumaeth Chavadej Chavadej, Sumaeth Siriphong Rojluechai Rojluechai, Siriphong Johannes W. Schwank Schwank, Johannes W. Vissanu Meeyoo Meeyoo, Vissanu 283

10 Epoxidation of Propylene with Oxygen-Hydrogen Mixtures Masatake Haruta Haruta, Masatake Jun Kawahara Jun, Kawahara 297

11 Propylene Epoxidation by O[subscript 2] + H[subscript 2] over Au Nanoparticles on Ti-Nanoporous Supports Ajay M. Joshi Joshi, Ajay M. Bradley Taylor Taylor, Bradley Lasitha Cumaranatunge Cumaranatunge, Lasitha Kendall T. Thomson Thomson, Kendall T. W. Nicholas Delgass Delgass, W. Nicholas 315

12 The Epoxidation of Propene over Gold Nanoparticle Catalysts T. Alexander Nijhuis Nijhuis, T. Alexander Elena Sacaliuc Sacaliuc, Elena Bert M. Weckhuysen Weckhuysen, Bert M. 339

13 Propylene Epoxidation via Shell's SMPO Process: 30 Years of Research and Operation J. K. F. Buijink Buijink, J. K. F. Jean-Paul Lange Lange, Jean-Paul A. N. R. Bos Bos, A. N. R. A. D. Horton Horton, A. D. F. G. M. Niele Niele, F. G. M. 355

14 Propylene Epoxidation with Ethylbenzene Hydroperoxide over Ti-Containing Catalysts Prepared by Chemical Vapor Deposition Kuo-Tseng Li Li, Kuo-Tseng Chia-Chieh Lin Lin, Chia-Chieh Ping-Hung Lin Lin, Ping-Hung 373

15 Metal Species Supported on Organic Polymers as Catalysts for the Epoxidation of Alkenes Ulrich Arnold Arnold, Ulrich 387

Sect. 4 Phase-Transfer Catalysis 413

16 Fine-Tuning and Recycling of Homogeneous Tungstate and Polytungstate Epoxidation Catalysts Paul L. Alsters Alsters, Paul L. Peter T. Witte Witte, Peter T. Ronny Neumann Neumann, Ronny Dorit Sloboda Rozner Rozner, Dorit Sloboda Waldemar Adam Adam, Waldemar Rui Zhang Rui, Zhang Jan Reedijk Reedijk, Jan Patrick Gamez Gamez, Patrick Johan E. ten Elshof Elshof, Johan E. ten Sankhanilay Roy Chowdhury Chowdhury, Sankhanilay Roy 415

17 Reaction-Controlled Phase-Transfer Catalysis for Epoxidation of Olefins Shuang Gao Shuang, Gao Zuwei Xi Xi, Zuwei 429

Sect. 5 Biomimetic Catalysis 449

18 Bio-Inspired Iron-Catalyzed Olefin Oxidations: Epoxidation Versus cis-Dihydroxylation Paul D. Oldenburg Oldenburg, Paul D. Ruben Mas-Balleste Mas-Balleste, Ruben Lawrence Que, Jr. Que, Lawrence, Jr. 451

19 Quantum Chemical Analysis of the Reaction Pathway for Styrene Epoxidation Catalyzed by Mn-Porphyrins Maria C. Curet-Arana Curet-Arana, Maria C. Randall Q. Snurr Snurr, Randall Q. Linda J. Broadbelt Broadbelt, Linda J. 471

Index 487


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Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis, The catalytic epoxidation of olefins plays an important role in the industrial production of several commodity compounds, as well as in the synthesis of many intermediates, fine chemicals, and pharmaceuticals. The scale of production ranges from millions , Mechanisms In Homogeneous And Heterogeneous Epoxidation Catalysis

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